Chemistry - Ch 3 Flashcards
Stoichiometry
Area of study that examines the quantities of substances consumed and produced in chemical reactions (from the Greek, stocheion “element” & metron “measure”)
Chemical equations
way to represent chemical reactions concisely
Reactants
starting substances in a chemical reaction
Products
substances produced in a chemical reaction
Coefficients
Numbers in front of a chemical formula
Combination reactions
2 or more substances react to form one product
Decomposition reaction
One substance undergoes a reaction to produce 2 or more other substances; common when heated
Combustion reactions
rapid reactions that produce a flame
Oxidation reactions
reactions that involve intermediate steps (like in the human body)
Quantitative significance
numbers in chemical formulas and chemical equations represent precise quantities
Formula weight
sum of the atomic weights of each atom in its chemical formula
Molecular weight
another name for formula weight if the chemical formula is that of a molecule
Formula units
because ionic substances exist as 3D arrays of ions, it’s inappropriate to call molecules; represented by the chemical formula of the substance (Ex. NaCl = 1 formula unit)
Percentage composition
percentage by mass contributed by each element in the substance; % element = (# atoms of that element)(atomic weight of each element)/(formula weight of the compound) x 100%
Mole (mol)
amount of matter that contains as many objects as the number of atoms in exactly 12g of isotopically pure Carbon12 (6.0221421 x 10^23)
Avogadro’s number (N subscript A)
6.0221421 x 10^23 (rounded = 6.02 x 10^23)
The mass of a single atom of an element (in amu) is numerically _____ to the mass (in grams) of 1mol of that element
equal
Molar mass
the mass in grams of one mole of a substance; the molar mass (in g/mol) of any substance is always numerically equal to its formula weight (in amu)
The ratio of the number of moles in each element in a compound gives the _____ in a compound’s empirical formula
subscripts; percent to mass, mass to mole, divide by small (divide by smallest number of moles to find whole numbers), multiply til whole (mass % elements –> (assume 100g sample) grams of each element –> use molar mass to figure moles of each element –> calculate mole ratio (finds empirical formula)
Whole number multiple formula
molecular weight/empirical formula weight
Empirical
“based on observation and experiment”
The coefficients in a balanced chemical equation indicate both the relative number of _____ in the reaction & the relative number of _______.
Molecules (formula units); moles
Combustion analysis
experimental technique to determine empirical formulas; commonly used for compounds principally containing carbon and hydrogen as their component elements
Limiting reactant/reagent
Reactant that is completely consumed in a reaction; limits the amount of product formed
Theoretical yield
Quantity of product that is calculated to form when all of the limiting reactant reacts
Actual yield
Amount of product obtained in a reaction
Percent yield
Actual yield compared to theoretical; % yield = actual yield/theoretical yield x 100%