Chemistry - Ch 17 Flashcards
Buffered solutions (buffers)
solutions which contain a weak conjugate acid-base pair can resist drastic changes in pH upon the addition of small amounts of strong acid or strong base
Common-Ion Effect
observation that whenever a weak electrolyte and a strong electrolyte contain a common ion, the weak electrolyte ionizes less than it would if it were alone in solution
Henderson-Hasselbalch Equation
pH = pKa + log [base/acid]
Buffer capacity
amount of acid or base the buffer can neutralize before the pH begins to change to an appreciable degree
pH range
range over which a buffer acts effectively
pH Titration Curve
a graph of the pH as a function of the volume of the added titrant
Solubility-product constant (solubility product)
Ksp; equilibrium constant describing how soluble the solid is in water
Complex ion
an assembly of a metal ion and the Lewis bases bonded to it
Formation constant
Kf; for a metal ion complex, the equilibrium constant for formation of the complex from the metal ion and base species present in solution; it is a measure of the tendency of the complex to form
Amphoteric oxides and hydroxides
substances capable of behaving as either an acid or base
Qualitative analysis
determines only the presence of absence of a particular metal ion
Quantitative analysis
determines how much of a given substance is present