One step forward and two steps back - An industrial perspective of chromite pre-oxidation Flashcards

1
Q

Die okaidasie van die Fe in die pellets, ekso of endotermies

A

Eksotermies

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2
Q

Formula of pure Chromite

A

FeO.Cr2O3

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3
Q

Wat is n beter chemiese voorstelling van ons erts?

A

(Fe2+,Mg2+)[Cr3+,Al3+,Fe3+]2O4

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4
Q

The oxidation process in simplified chemical form:

A

Spinel + O2 = M2O3 (sesquioxide) + altered spinel

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5
Q

Beweging van die ione tussen die spinel and sesquioxide

A

So jy ontrek yster en vorm dan n yster ryk sesquioxide fase (Fe,Cr,Al)2O3. Die spinel wat oorbly het dan n hoer konsentrasie Mg2+ ione

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6
Q

So as jy na die spinel kyk wat oorbly, watter Fe atome is verwyder?

A

Meestal die Fe2+ ione. Die Fe3+ in oktahedriese posisies bly

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7
Q

Proximate analysis

A

Includes moisture, volatiles, ash and fixed carbon

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8
Q

First step in analysing coals are? And for what purpose?

A

Drying at temperatures not exceeding 40C to determine free moisture content

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9
Q

How is the inherent moisture determined?

A

The dried sample is now prepared, milled etc and dried at 105C, the mass loss is associated with the inherent moisture

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10
Q

Kam daar nog water wees buiten die free moisture en inherent moisture?

A

Jip, by hoer temperature kan daar kristalwater vrygestel word, maar word dan beskou as deel van die volatiles

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11
Q

Hoe word die fixed carbon bereken?

A

100 - (Moisture + Volatiles + Ash)

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12
Q

Na die inherent moisture, hoe word die volatile content bereken?

A

Mass loss by 900C vir 7min

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13
Q

Hoe word die ash content bepaal.

A

By 850 grade word daar dan n oksiderende omgewing geskep. Die minerale wat oorbly staan bekend as die as

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14
Q

Vir modellering, wat is beter, die proximate of die ultimate analysis?

A

Ultimate - want die fixed carbon kan ook nog ander elemente bevat

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15
Q

Op watter beginsel werk die ultimate analysis?

A

Daar werk jy die persentasie suurstof uit: O2% = 100-inherent moisture-ash-C- H - N - S

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16
Q

Watter steenkool het meer inertiniet, Vrystaant of Mpumulanga?

A

Vrystaat

17
Q

Sulphur in coal can exist in three forms?

A

Pyritic (bond to Fe)
Sulphatic
Organic