Molec Shape And Bond 2 Flashcards

1
Q

Is the average distance from nucleus of an electron in a 2s orbital greater/lower than for an electron in an 1s orbital.
Why?

A

Greater
As 2s is a larger sphere
Average electron density is lower in 2s

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2
Q

Where is the electron in 1s orbital

A

Anywhere in the sphere

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3
Q

In a 2s atomic orbital what is the region called where the electron falls to 0

A

Node

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4
Q

What is the node in terms of waves

A

Where there is no transverse displacement

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5
Q

Describe the MO theory

A

AO are combined to make MOs

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6
Q

Valence-bond theory

A

Electrons within the molecule remain in the AO but we don’t know which AO

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7
Q

What molecule provides an accurate MO calculation

A

H2+

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8
Q

What is the main rule of MO

A

Same number of MOs as starting AOs

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9
Q

If you add wave functions what do you get

A

Bonding MO

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10
Q

Subtracting wave functions leads to what

A

Anti-bonding molecular orbitals

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11
Q

Anti bond orbital has a node and the electrons are likely to be found anywhere but between the nuclei
True/false

A

True

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12
Q

Electrons in bond orbital most likely to be found between the nuclei
True/false

A

True

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13
Q

What does end on 2p orbitals lead to

A

Sigma bonds

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14
Q

What does side on 2p orbitals lead to

A

Pie bonds

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15
Q

What is stronger sigma or pie

A

Sigma

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16
Q

In carbon hybridisation we can mix 2s and 2p orbitals to create 4 new degenerate hybrid orbitals. What are these hybrid orbitals called

A

Sp3

17
Q

In sp3 what is the ration of s to p

A

1/4 s

3/4 p

18
Q

If there is 2 electro groups give the electron geometry, bond angle and hybridisation.

A

Linear
180
Sp

19
Q

If there is 3 electro groups give the electron geometry, bond angle and hybridisation.

A

Trigonal planar
120
Sp2

20
Q

If there is 4 electro groups give the electron geometry, bond angle and hybridisation.

A

Tetra
109.5
Sp3