Carboxylic acids Flashcards
Longer carbon chains increase the molecule’s solubility in
Nonpolar organic solvents
The carboxylic acid that will yield the least amount of protons in solution will be the
Least acidic molecule
Chloro substituents are
Electron withdrawing
A carboxylic acid with a longer carbon chain is
Less acidic
Why are longer carboxylic acids less acidic?
There is a greater induction of electrons destabilizing the conjugate base anion
How are the pKas of -COOH compared to alcohols?
Lower than alcohols due to donation of protons
What happens when water reacts with Acid Chlorides?
-COOH are formed
The hydroxyl oxygen in carboxylic acid is
Nucleophilic
What undergo decarboxylation upon the addition of heat energy?
Beta keto acids
What is more soluble in polar solvents?
Shorter chains