Bioenergetics Flashcards
A reaction with a large positive change in free energy is
Extremely unfavorable
An unfavorable reaction has an equilibrium constant between
Zero and 1
An endothermic reaction has a
Positive change in enthalpy, or +∆H
How is the change in free energy for exergonic reactions?
Negative, -∆G
A negative change in free energy (-∆G) represents a
Spontaneous reaction
Spontaneous reactions have equilibrium constants that are
Greater than 1
ATP hydrolysis refers to the reaction that
Cleaves the phosphoanhydride bond that results in a phosphate molecule and ADP as products
ATP hydrolysis involves the hydrolysis of the
Phosphoanhydride bond linking the gamma phosphate to the beta phosphate
A spontaneous reaction always
Decreases free energy ∆G of the system
The standard reduction potential is a measure of the
Tendency of a chemical species to be reduced
How many Pi are in ADP?
2
How many Pi are in ATP?
1
The free energy stored by ADP is
Positive and greater that the free energy stored by AMP
One would expect ATP hydrolysis to be non-spontaneous when
ATP concentration is very far below equilibrium concentration and ADP concentration is very far above equilibrium concentration
Spontaneous reactions have products that have a
Lower energy compared to reactants