Chem Ch 8a quiz Flashcards
What are oxidation numbers
Possible charges an atom of an element can have (if all its bonds are ionic)
Why do we have oxidation numbers
Keep track of electrons in bonding of 2 atoms
Represent number of electrons that an atom in a compound must gain or lose to return to its neutral state (charge = 0)
Determining the oxidation number rules
1) (free-element rule): Pure elements + Atoms in natural form = 0
2) (ion rule): Monatomic ion is = ion’s charge
3) (zero-sum rule): Sum of all atom’s #s must be 0
4) Alkali metals +1, Alkaline earth +2, Hydrogen +1 (except when bonded to atoms -1)
Oxygen -2 (except when bonded to fluorine +1; -1 in peroxide ion)
Halogens -1 when bonded to metals, w nonmetals the element w higher electronegativity takes negative #
Fluorine ALWAYS -1 (Also Cl, Br, I)
5) Oxidation #s of all atoms in a polyatomic ion = its charge
(Also used 4 poly ionic compounds)
Finding oxidation numbers
If 1 rule contradicts another rule, rule listed first is followed
For binary ionic compounds, crisscross method can be used
Polyatomic ions are covalently bonded groups of atoms that carry a ____________
Charge
Some atoms can have more than one
Oxidation #
EX: Transition metals
Iron (Fe): +2, +3, +6
Nitrogen (N): -3, +5
Polyatomic ions are what kind of groups that carry what?
Covalently bonded groups of atoms that carry a charge