Fuels Flashcards

1
Q

what is crude oil

A

complex mixture of lots of different hydrocarbon compounds of different sizes

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2
Q

what are chains and rings

A

The hydrocarbon molecules in crude oil consist of a carbon backbone which can be in a ring or chain, with hydrogen atoms attached to the carbon atoms
The mixture contains molecules with many different ring sizes and chain lengths

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3
Q

what is crude oil useful for

A

It is also a main source of raw materials (called feedstock) for the petrochemical industry and petrol and diesel

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4
Q

why is crude oil finite

A

it is being used up much faster than it is being formed

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5
Q

explain the process of fractional distillation of crude oil

A

Fractional distillation is carried out in a fractionating column which is very hot at the bottom and cool at the top

Crude oil enters the fractionating column. vapours rise

Vapours of hydrocarbons with very high boiling points will immediately condense into liquid lower down due to high temperatures, and longer hydrocarbons

Vapours of hydrocarbons with low boiling points will rise up the column and condense at the top to be tapped off and shorter hydrocarbons

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6
Q

recall the names of the fractions

A
refinery gas - bottle gas / domestic
petrol - cars
kerosene - aircraft
diesel - cars larger 
fuel oil - ships / power stations
bitumen -  roads roofs
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7
Q

What are the three factors that size of hydrocarbons depend on

A

boiling point - As the molecules get larger, the intermolecular forces of attraction between the molecules becomes greater as there is more surface area contact between them

viscosity - ease of flow of a liquid
High viscosity liquids are thick and flow less easily
Viscosity also increases with increasing chain length

Flammable - Smaller hydrocarbon molecules are more flammable and are easier to ignite than larger molecules

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8
Q

what is the homologous series

A

groups of organic compounds that have similar features and chemical properties

The same general formula

The difference in the molecular formula between one member and the next is CH2

As the molecules get larger, the intermolecular forces of attraction between the molecules becomes greater ,more heat is needed to separate the molecules, increasing molecular size there is an increase in boiling point

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9
Q

what does complete combustion release

A

carbon dioxide and water

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10
Q

what does incomplete combustion release

A

carbon monoxide, (toxic) and carbon (soot)

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11
Q

what does carbon monoxide do

A

binds onto haemoglobin or red blood cells preventing blood from doing job of carrying oxygen leading to fainting , coma death

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12
Q

what does carbon do

A

carbon released and deposit as soot reduces air quality and makes it dirty

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13
Q

what is sulphur dioxide

A
  • formed from impurities in fossil fuels when they are burnt

mixes w clouds and fall as acid rain causes lakes to become acidic killing animals and damaging trees and limestone buildings

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14
Q

what does nitrogen dioxide do

A

produced from car engines reacts with rain water to form a mixture of nitrous and nitric acids, which contribute to acid rain:

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15
Q

what are two advantages of hydrogen fuel

A
  • very clean only waste is water

- hydrogen is obtained from water which is renewable and also obtained from waste product

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16
Q

what are disadvantages of hydrogen fuel

A
  • expensive and uses energy from other resource

- hard to store

17
Q

what is cracking

A

when long saturated molecules into smaller unsaturated molecules and alkane

18
Q

by what method does cracking occur

A
  • thermal decomposition when substance breaks down when you heat it so break covalent bonds requiring energy
19
Q

why is cracking important

A

more demand for petrol diesel and alkenes produce polymers

20
Q

how does cracking occur

A

hydrocarbons passed over aluminium oxide at 400 - 700 at 70atm