Semester Exam Review Flashcards

1
Q

which SI prefix means “one million” or 10^6?

A

mega-

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2
Q

which SI prefix means “one billionth” ore 10^-9

A

nano-

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3
Q

which SI prefix means “one millionth” or 10^-6?

A

micro-

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4
Q

meters in a kilometer

A

1000

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5
Q

a millimeter is what fraction of a meter?

A

1/1000

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6
Q

centimeters in a meter

A

100

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7
Q

a lowercase letter m is the symbol of which SI prefix

A

milli-

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8
Q

symbol for the prefix centi-

A

c

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9
Q

carbon

A

C

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10
Q

chlorine

A

Cl

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11
Q

aluminum

A

Al

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12
Q

hydrogen

A

H

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13
Q

oxygen

A

O

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14
Q

iron

A

Fe

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15
Q

potassium

A

K

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16
Q

sodium

A

Na

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17
Q

calcium

A

Ca

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18
Q

neon

A

Ne

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19
Q

Cu

A

copper

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20
Q

Ag

A

silver

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21
Q

Si

A

silicon

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22
Q

He

A

helium

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23
Q

Zn

A

zinc

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24
Q

Co

A

cobalt

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25
Q

U

A

uranium

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26
Q

Pb

A

lead

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27
Q

Hg

A

mercury

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28
Q

F

A

fluorine

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29
Q

subatomic particle of the atom that has no electric charge

A

neutron

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30
Q

phenomenon that consists of electrons flowing between electrodes in a vacuum tube

A

cathode rays

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31
Q

type of particle that nucleons are believed to be made of

A

quarks

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32
Q

if there is a + after an element, than there will one ______________ electron than proton

A

LESS

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33
Q

equation to determine number of neutrons in an element

A

N= A (top number) - Z (lower number)

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34
Q

proposed the planetary model of the atom

A

Rutherford

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35
Q

experiment used to determine the electron’s charge

A

oil-drop experiment

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36
Q

this value is the number of nucleons in an atom

A

mass number

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37
Q

atoms of the same element that have different numbers of nucleons

A

isotopes

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38
Q

the prefix deca- in a molecular formula indicates that ___________ atoms of that element are present in each molecule

A

10

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39
Q

hepta-

A

7

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40
Q

nona-

A

9

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41
Q

octa

A

8

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42
Q

compound consisting of two nitrogen atoms and four oxygen atoms is named

A

dinitrogen tetroxide

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43
Q

compound consisting of two nitrogen atoms and five oxygen atoms

A

dinitrogen pentoxide

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44
Q

compound consisting of a carbon atom and four fluorine atoms is named

A

carbon tetrafluoride

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45
Q

compound consisting of a sulfur atom and six fluorine atoms is

A

sulfur hexafluoride

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46
Q

diphosphorus tetraiodide

A

P2 I4

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47
Q

diiron hexachloride

A

Fe2 Cl6

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48
Q

hydroxide

A

OH-

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49
Q

nitrate

A

NO3-

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50
Q

chlorate

A

ClO3-

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51
Q

ammonium

A

NH4+

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52
Q

bicarbonate

A

HCO3-

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53
Q

sulfate

A

SO4 2-

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54
Q

carbonate

A

CO3 2-

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55
Q

iron (III)

A

Fe 3+

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56
Q

silicate

A

SiO3 2-

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57
Q

phosphate

A

PO4 3-

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58
Q

the principle requiring that chemical reactions be balanced is the law of conservation of

A

mass

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59
Q

a symbolic representation of a chemical reactions is a

A

chemical equation

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60
Q

when writing a chemical reaction, the _________ are on the left and the _____________ are on the right

A

reactants- left
products- right

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61
Q

A + B —–> AB

A

combination reaction

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62
Q

AB ————-> A + B

A

decomposition reaction

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63
Q

AB + CD —————-> AD + CB

A

double-displacement reaction

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64
Q

AB + C ————–> A + BC

A

single-displacement reaction

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65
Q

According to Boyle’s law, if the pressure upon a gas INCREASES, the volume will

A

decrease (indirect proportioned)

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66
Q

According to Charle’s law, if the temperature of a gas is INCREASES, the volume will

A

increase (direct proportioned)

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67
Q

if the temperature of a gas is increases while its volume remains constant, its pressure will

A

increase

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68
Q

in the ideal gas law, the constant R is the ___________

A

universal gas constant

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69
Q

According to _________________ law, equal volumes of gases at the same temperature and pressure have the same number of molecules

A

Avogadro’s law

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70
Q

the acronym STP stands for

A

standard temperature and pressure

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71
Q

the molar volume of an ideal gas under STP conditions is about

A

22.4 L/mol

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72
Q

law that says that when gases react the volumes of reactants and products are in small, whole-number ratios

A

Gay-Lussac’s Law

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73
Q

the number of this type of particle identifies an atom as a given element

A

protons

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74
Q

type of chemist that would most likely study alcohols, which consist of carbon, hydrogen, and oxygen

A

organic chemist

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75
Q

indicates a chemical change

A
  1. change in color
  2. formation of gas
  3. formation of precipitate
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76
Q

group of two or more atoms linked together by chemical bonds

A

molecule

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77
Q

relative charge of an electron

A

-1

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78
Q

developed the atomic theory of matter

A

John Dalton

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79
Q

a homogenous part of a system that is in contact with but physically distinct from other parts of the system

A

phase

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80
Q

a measure of the force of gravity upon an object is

A

weight

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81
Q

as the internal kinetic energy of a substance increases, the substance’s temperature

A

INCREASES

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82
Q

the discovery of the nucleus and the development of the planetary model of the atom were results of the

A

gold-foil experiment

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83
Q

the smallest particles into which a compound may be broken down without changing it into another substance are

A

molecules

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84
Q

the general term for techniques of separating liquids based on their boiling points is

A

distillation

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85
Q

an ion that 3 protons, 4 neutrons, and 2 electrons is a

A

cation

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86
Q

best explanation as to why liquid becomes a gas at the boiling point

A

the kinetic energy of the particles is great enough to overcome their attraction of each other

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87
Q

term refers to the ration of an object’s mass to its volume

A

density

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88
Q

refers to energy that is possessed by matter due to its motion

A

kinetic

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89
Q

which of the three main particles composing that atom has the smallest mass

A

electron

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90
Q

value of Avogadro’s number

A

6.022 x 10^23

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91
Q

if the empirical formula of a substance is known, what additional information is needed to calculate the molecular formula

A

molar mass

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92
Q

unit that is equivalent to Avogadro’s number of objects

A

molle

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93
Q

set of symbols that tells how many of each type of atom are found in a molecule

A

formula

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94
Q

sum of the atomic masses of all the atoms in a molecule

A

mass

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95
Q

the smallest particles into which an element may be broken down without changing the identity of the element

A

atoms

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96
Q

1 millimeter of mercury is equal to

A

1 torr

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97
Q

number of protons in an atom

A

atomic number

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98
Q

standard atmosphere equals

A

760 torr

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99
Q

the isotope that the atomic mass unit is relative to

A

carbon-12

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100
Q

standard pressure and temperature

A

273.15 K and 760 torr

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101
Q

number of atoms in exactly one mole of atoms

A

6.022 x 10^23

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102
Q

the instrument used to measure atmospheric pressure

A

barometer

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103
Q

amount of force exerted upon a surface per unit area is

A

pressure

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104
Q

in the ___________ state of matter, particles have enough energy to move freely but not enough energy to overcome their attraction for each other

A

liquid

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105
Q

how closely a measured value matches the actual value is

A

accuracy

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106
Q

the dense central portion of an atom is called the

A

nucleus

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107
Q

the link between the microscopic and the macroscopic levels of chemistry is

A

Avogadro’s number

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108
Q

which law implies that at constant temperature and pressure, the molar volume of an ideal gas is constant

A

Avogadro’s law

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109
Q

negatively charged subatomic particles in an atom

A

electrons

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110
Q

the type of energy associated with motion is called

A

kinetic energy

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111
Q

the type of energy associated with the position of an object relative to the forces upon it is known as

A

potential energy

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112
Q

in thermodynamics, the portion of the universe of the sample of matter being studied is referred to as the

A

system

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113
Q

according to the first law of thermodynamics, the change in internal energy is the sum of

A

heat and work

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114
Q

the SI unit of work and energy

A

joule

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115
Q

the thermodynamic function denoted by the symbol H, which takes into account internal energy (E), volume (V), and pressure (P), is

A

enthalpy

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116
Q

a chemical reaction that can be summarized by the formula
reactants + heat ———————-> products is an

A

endothermic equation

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117
Q

reactants——————–> products + heat

A

exothermic reaction

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118
Q

heat required to raise the temperature of a unit mass of a substance by a unit temperature is the

A

specific heat

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119
Q

device in which energy changes during a chemical reaction may be measured is the

A

calorimeter

120
Q

the highest or peak point on a wave is the wave’s

A

crest

121
Q

the distance between any two corresponding points on successive waves is the

A

wavelength

122
Q

the number of complete waves that pass by a point in a given time is the wave’s

A

frequency

123
Q

individual “bundles” or quanta of light energy are called

A

photons

124
Q

an arrangement of all forms of electromagnetic radiation in order of frequency and wavelength

A

electromagnetic spectrum

125
Q

SI unit of frequency

A

Hertz

126
Q

height of the wave

A

amplitude

127
Q

the particle theory of light was first propsed by

A

Isaac Newton

128
Q

the amount of energy an individual quantum of light contains depends on its

A

frequency

129
Q

the speed of light in a vacuum is approximately

A

3.00 x 10^8 m/s

130
Q

quantum number that describes the orientation of an orbital in space

A

magnetic quantum number (ml)

131
Q

quantum number describes the shell in which an electron is located

A

principal quantum number (n)

132
Q

states that no two electrons in the same atom have the same four quantum numbers

A

Pauli exclusion principle

133
Q

states that a single electron occupies each orbital within a subshell before electrons begin pairing

A

Hund’s rule

134
Q

specifies the order in which subshells fill with electrons

A

aufbau principle

135
Q

type of orbital that has a spherical shape

A

s

136
Q

the second shell from the center of an atom can hold up to ______________ electrons

A

8

137
Q

the complete arrangement of electrons in an atom is the atom’s

A

electron configuration

138
Q

the outermost electrons which are involved in chemical reactions

A

valence electrons

139
Q

how many electrons are in the 2p subshell of a nitrogen atom?
1s^2 2s^2 2p^3

A

3

140
Q

the energy required to remove an electron from an atom

A

ionization energy

141
Q

describes how strongly a chemically combined atom draws electrons to itself

A

electronegativity

142
Q

which are larger, simple cations or the neutral atoms from which they were formed?

A

neutral atoms

143
Q

periodic trend: decreases down, increases across

A

ionization energy, electron affinity, electronegativity

144
Q

periodic trend: increases down, decreases across

A

atomic radii, metallic character

145
Q

refers to the randomness of a substance or system

A

entropy

146
Q

internal energy of a system plus the product of its pressure and volume

A

enthalpy

147
Q

energy is commonly defined as

A

the ability to do work

148
Q

device used to measure heat flow during physical processes or chemical reactions

A

calorimeter

149
Q

the change in a system’s internal energy is the sum of the heat added to the system and the work done on the system is the ____________ law of thermodynamics

A

1st

150
Q

chemical and physical changes that release heat are known as

A

exothermic processes

151
Q

the field of chemistry that deals with the energy changes in chemical reactions is chemical

A

thermodynamics

152
Q

chemical reactions and physical changes that absorb heat are known as

A

endothermic processes

153
Q

type of energy associated with position relative to a force is

A

potential energy

154
Q

an endothermic reaction is characterized by ______________ change in enthalpy

A

positive

155
Q

the enthalpy of formation for any element in its standard state is

A

0

156
Q

when a cup of water evaporates into water vapor, the entropy change in the system is

A

positive

157
Q

at constant pressure, enthalpy change equals

A

heat

158
Q

the heat per unit mass required to vaporize a substance at its normal boiling point is

A

heat of vaporization

159
Q

the total amount of heat liberated or absorbed because of a chemical reaction

A

heat of reaction

160
Q

the heat per unit mass required to melt a substance at its normal melting point

A

heat of fusion

161
Q

the amount of heat required to cause a unit rise in temperature of a unit mass of a substance

A

specific heat

162
Q

individual packets of light energy

A

photons

163
Q

amplitude of wave is the measure of its

A

strength

164
Q

if the wavelength of a light wave decreases, how must its frequency change

A

increase

165
Q

light consists of

A

electromagnetic waves
photons

166
Q

developed the periodic table of the elements

A

Mendeleev

167
Q

unit wave frequency is measured in

A

hertz

168
Q

the lines in the hydrogen spectrum represent

A

photons emitted as electrons drop from higher to lower energy levels

169
Q

consists of elements that usually exist as 2+ ions

A

alkaline earth metals

170
Q

the lowest energy state of an atom

A

ground state

171
Q

the elements in column 1 are the

A

alkali metals

172
Q

the elements in column 2 are the

A

alkaline earth metals

173
Q

the elements in column 17 are the

A

halogens

174
Q

the elements in column 18

A

noble gases

175
Q

elements in columns 1, 2, and 13-18 are all classified as

A

main-group elements

176
Q

probable formula for the bromide of beryllium

A

1234321 (Br= 1; Be= 2) therefore BeBr2

177
Q

not an alkali metal

A

calcium

178
Q

when an element is vaporized and heated in a flame or an electric arc, the light emitted forms a

A

line spectrum

179
Q

characterized by the transfer of electrons from one atom to another

A

ionic bond

180
Q

characterized by the sharing of a “sea” of delocalized electrons among many atoms

A

metallic bond

181
Q

produces substances that are characteristically malleable and ductile

A

metallic bond

182
Q

bond in which cations are attracted to anions

A

ionic bond

183
Q

states that atoms tend to react to achieve a noble-gas electron configuration

A

octet rule

184
Q

unequal sharing of electrons produces a

A

polar bond

185
Q

a bond that involves sharing of four electrons

A

double covalent bond

186
Q

a bonding situation in which electrons are shared by more than two atoms is known as

A

delocalization

187
Q

electrons that circulate freely through a molecule instead of being bound to a single atom or pair of atoms are said to be

A

delocalized (resonant)

188
Q

a molecule that has a symmetrical distribution of polar covalent bonds will be ______________ as a whole

A

nonpolar

189
Q

a formula in which nonbonding electrons are shown as dots around atoms and bonds are shown as lines or dots between atoms is a

A

Lewis structure

190
Q

tetrahedral

A

4 bonds
0 nonbonds
polar or nonpolar

191
Q

trigonal pyramidal

A

3 bonding
1 nonbonding
always polar

192
Q

trigonal planar

A

3 bonding
0 nonbonding
polar or nonpolar

193
Q

angular

A

2 bonding
2 nonbonding
always polar

194
Q

linear

A

1 or 2 bonding
0 nonbonding
polar or nonpolar

195
Q

why one group would be polar and the other not

A

arranged symmetrically vs. asymmetrically

196
Q

superior system of measurement because of its divisibility

A

metric system

197
Q

metric unit of mass

A

kilogram

198
Q

metric unit of length

A

meter

199
Q

10^-3

A

milli-

200
Q

temperature scale for scientific measurement

A

Kelvin

201
Q

makes numbers more manageable

A

scientific notation

202
Q

numbers that are always significant

A

1-9

203
Q

most abundant state of matter in the universe

A

plasma

204
Q

smallest whole/complete particle

A

atoms

205
Q

subatomic particles

A

proton (+)
electron (-)
neutron

206
Q

chemical grouping of different types of atoms

A

compounds

207
Q

mixture that is the same throughout

A

homogenous

208
Q

mixture that is different throughout

A

heterogenous

209
Q

change in state of matter

A

physical change

210
Q

burn wood

A

chemical change

211
Q

boil water into gas

A

physical change

212
Q

processes used to separate mixture

A

distillation, chromatography

213
Q

discovered the electrons

A

Thompson

214
Q

discovered proton

A

Rutherford

215
Q

discovered the neutron

A

Chadwick

216
Q

shows number of protons

A

atomic number (Z)

217
Q

the sum of neutrons and protons

A

mass number (A)

218
Q

average mass of all isotopes

A

atomic mass

219
Q

two types of chemical formulas

A

molecular, empirical

220
Q

1 mole of substance =

A

Avogadro’s number

221
Q

chemical changes caused by collisions between atoms/ molecules

A

chemical reaction

222
Q

reactants on the ______________
products on the ______________

A

left
right

223
Q

the reactant giving the smallest amount of production is the

A

limiting reactant

224
Q

solid to liquid

A

heat of fusion

225
Q

absorbs heat; cold to touch

A

endo-

226
Q

product; releases energy

A

exo-

227
Q

increases entropy

A

exothermic

228
Q

reverse processes that don’t seem natural

A

spontaneity

229
Q

states you can’t simultaneously know position and momentum of an electron

A

uncertainty principle

230
Q

3D regions of probability

A

orbitals

231
Q

2D pathway

A

orbit

232
Q

tells chem properties and where the electrons are located

A

electron configuration

233
Q

V and T are _______________ related

A

directly

234
Q

units of pressure

A

pascal, torr atmosphere

235
Q

measures pressure but does not require fluid

A

aneroid barometer

236
Q

standard pressure

A

1 atm, 760 torr

237
Q

measure pressure of gas sample

A

monometer

238
Q

P and V are inversely related at constant T

A

Boyle’s Law

239
Q

T and V are directly related at constant P

A

Charle’s law

240
Q

temperature scale needed for the gas laws

A

Kelvin

241
Q

constant T, P, V

A

Avogadro’s law

241
Q

small whole number ratios

A

Gay-Lusac’s law

242
Q

1 mole of gas at STP =

A

22.4 L

243
Q

combines Boyle, Charles, and Avogadro’s law

A

ideal gas law

244
Q

PVnRT

A

n= number of moles
R= universal gas constant (o.0821 L x atm/K x mol

245
Q

mixing of gas by random molecular motion

A

diffusion

246
Q

states that the heavier the gas the slower the rate of diffusion

A

Graham’s law of diffusion

247
Q

states that the total pressure of gas = sum of all individual parts of pressure

A

Dalton’s law of partial pressure

248
Q

1 calorie =

A

4.184 J

249
Q

states that energy of the unierse is conserve

A

1st law of thermodynamics

250
Q

total heat energy content of the system

A

enthalpy

251
Q

exothermic has _ enthalpy

A

negative

252
Q

a negative change in enthalpy is in ________________ in entropy

A

increase

253
Q

specific heat of water

A

4.18 J/g x C

254
Q

when the word heat is added

A

thermochemical equation

255
Q

in fusion and vaporization, the _____________ does not change; the _________________ changes the ______________

A

temperature not change
energy changes state

256
Q

Gibbs free energy helps determine

A

spontaneity

257
Q

delta G is 0

A

equilibrium

258
Q

-delta G

A

spontaneous

259
Q

+ delta G

A

nonspontaneous

260
Q

at a constant speed, wavelength and frequency are

A

inverse

261
Q

max displacement

A

amplitude

262
Q

particle theory of light

A

Newton

263
Q

wave theory of light

A

Huygens

264
Q

wave-particle duality

A

Einstein

265
Q

electromagnetic waves

A

Maxwell

266
Q

causes light to be emitted in LINE spectrum

A

excited and dropped to ground state

267
Q

Bohr’s model proposed

A

energy levels

268
Q

Schrodinger model

A

wave-mechanical model

269
Q

Born’s Model

A

electron-cloud model

270
Q

subshel shapes

A

s, p, d, f

271
Q

determines the number of valence electrons

A

group

272
Q

filling up from lowest to highest

A

aufbau

273
Q

high EN

A

high ability to pull electrons to self

274
Q

hydrogen bonded to _______ _____________ or __________ makes it a hydrogen bond

A

N, O, F

275
Q

strongest intermolecular force

A

hydrogen bond

276
Q

weakest intermolecular force; occurs in all atoms, molecules etc

A

London forces

277
Q

present when molecules are polar; EN

A

dipole-dipole force

278
Q

bonding present when greater than 1.7

A

ionic

279
Q

bonding present when less than 1.7

A

covalent

280
Q

determines type of bonding

A

electronegativity difference

281
Q

only elements that do not require 8 valence electrons

A

hydrogen H
helium HE

282
Q

states that nonbonding pairs have more force than bonding

A

VSEPR (valence-shell electron-pair repulsion)

283
Q

Atoms will tend to react chemically so as to achieve a noble-gas electron configuration, either by losing or gaining electrons with other atoms

A

Octet rule

284
Q

How do ionic and covalent bonds differ in the electron rearrangements involved?

A

Ionic bonding- electrons transferred
Covalent bonding- electrons shares

285
Q

Why do covalent networks such as diamond and silicon carbide tend to be very hard?

A

Billions and trillions of atoms are joined into one unit by strong covalent bonds.

286
Q

Primary difference between covalent and metallic bonding—

A

Covalent bonding involves the sharing of electrons

Metallic bonding involves the sharing of delocalized electrons among large number of atoms

287
Q

Type of covalent bond that forms a dipole

A

Polar bond

288
Q

How is resonance indicated when drawing Lewis structures?

A

Double-headed arrows between Lewis structures

289
Q

How does an intermolecular force differ from a chemical bond?

A

Intermolecular forces physically attract molecules to each other without transfer or sharing of electrons

Chemical bonds chemical bond atoms into compounds through the transfer or sharing of electrons

290
Q

What is the difference between crystalline and amorphous solids at the molecular level? How does this affect the properties of the substances?

A

Crystalline solid has particles arranged in a regular and repeated 3D pattern; definite melting point

Amorphous solids have no ordered arrangement or pattern for the particles that compose it; has not definite melting point.

291
Q

Three main types of cubic unit cells

A

Body-centered cubic
Face-centered cubic
Simple unit cell

292
Q

Cubic close packing

A

Face-centered cubic

293
Q

The bcc’s atoms has ________ identical neighbors

A

8

294
Q

The fcc’s and hcp’s atoms have _____________ identical neighbors

A

12

295
Q

The simplest repeating unit in a crystal is called the

A

Unit cell