Section 16.1 - Oxidation and Reduction Processes Flashcards
chemical reactions that involve a change in the electron configurations of the reacting substances are
oxidation-reduction reactions (redox reactions)
any process in which an atom loses one or more electrons
oxidation
any process in which an atom gains one or more electrons
reduction
LEO GER
Loss of Electrons = Oxidation
Gain of Electrons = Reduction
the reactants in a redox reaction may be viewed as
acting upon each other to cause the reaction
redox is
change in the electronic structure
one reactant that cases oxidation by accepting electrons from the other reactant, reducing in the process
oxidizing agent
reaction that causes reduction by giving up electrons for other reactant to accept, oxidizing in the process
reducing agent
oxidation and reduction occur
simultaneously
the reducing agent is __________ and the oxidizing agent is ____________
oxidized
reduced
the charge the atom is assumed to have in a particular ion or compound
a result of assigning valence electrons to the more electronegative element involved in a bond
oxidation number
Rules for Assigning Oxidation Numbers:
- the oxidation number of any element in its uncombined state is 0
- the oxidation number of a monoatomic (one-atom) ion is equal to charge
- Hydrogen has an oxidation number of +1 in most of its compounds
- oxygen is assigned an oxidation of -2 in most of its compounds
- halogens in their compounds are assigned oxidation number of -1 unless they are bonded to a more electronegative halogen or to oxygen
- alkali metals (G1), alkaline earth metals (G2), and aluminum (G13) in their commpounds have positive oxidation numbers equal to the number of valence electrons in the neutral atom
- the algebraic sum of the oxidation numbers of all the atoms in a molecule or polyatomic ion MUST EQUAL THE CHARGE ON THAT PARTICLE
find oxidation numbers
CO2
1. charge = 0
2. (1xC) + (2 x -2) = 0
3. C = -3 O= -2
is a process in which the oxidation number increases
(becomes more positive)
oxidation
process in which the oxidation number decreases (becomes more negative)
reduction
in a balanced redox equation, the ________________ in oxidation numbers must equal the _____________ in oxidation numbers
total decrease = total increase