Section 12.4- Colligative Properties Flashcards

1
Q

any property that depends on the number of particles and not on the identity or properties of the particles is a

A

colligative property

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2
Q

important colligative properties

A
  1. vapor pressure lowering
  2. freezing point depression
  3. boiling point elevation
  4. osmotic pressure
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3
Q

vapor pressure is a

A

dynamic equilibrium (rate of condensation and rate of evaporation are equal)

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4
Q

at equilibrium the number of molecules evaporating and the number of molecules condensing are

A

EQUAL

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5
Q

the pressure exerted by the vapor when a liquid phase and vapor phase are in equilibrium is the

A

vapor pressure

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6
Q

may be considered a measure of the escaping tendency of molecules in the liquid

A

vapor pressure

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7
Q

the higher the vapor pressure, the easier it is for

A

a liquid to escape and become a gas

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8
Q

the lower the vapor pressure, the harder it is for

A

liquid to escape and become a gas

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9
Q

a gas is highly influenced by

A

temperature and pressure

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10
Q

the higher the temperature, the higher the

A

vapor pressure

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11
Q

the addition of a nonvolatile solute to a solvent _________________ the tendency of the solvent molecules to escape from the surface of the liquid

A

reduces

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12
Q

a nonvolatile solute _______________ the vapor pressure of the solvent

A

lowers

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13
Q

using a nonvolatile solute lowers the vapor pressure requires a

A

higher temperature to boil

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14
Q

the vapor pressure lowering has an effect on

A

both the boiling and freezing points of the solution

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15
Q

the lowering of vapor pressure in solutions is a

A

colligative property

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16
Q

the temperature at which the vapor pressure of the liquid equals the atmospheric pressure

A

boiling point of a liquid

17
Q

if the atmospheric pressure is 1 atm, the temperature is the

A

normal boiling point

18
Q

the boiling point when a nonvolatile solute is present is

A

boiling point elevation (delta Tb)

19
Q

the temperature at which the vapor pressures of the solid and liquid are equal

A

freezing point

20
Q

the resulting phenomenon when the vapor pressure is lowered due to the presence of a solute and in turn lowers the freezing point of the solvent

A

freezing point depression (delta Tf)

21
Q

boiling point elevation and freezing point depression are

A

colligative properties

22
Q

constant values are associated with each solvent and known as the

A

molal boiling point elevation constant (Kb)
molal freezing point depression constant (Kf)

23
Q

equation for the constants of freezing and boiling

A

delta Tb= mKb
delta Tf= mKf

24
Q

to find the actual boiling point or freezing point of a given solution, the freezing point depression must be ________________ the normal freezing point, and the boiling point elevation must be _____________________ the normal boiling point

A

*subtracted from (normal freezing point - freezing point depression)

*added to (boiling point elevation + normal boiling point)

25
Q

substances that do not ionize or dissociate in aqueous solutions to produce ions that can conduct an electrical current are

A

nonelectrolytes

26
Q

compounds that dissolve in water to produce ions that can conduct electrical current are

A

electrolytes

27
Q

dissociate or ionize essentially completely in water to give solutions that are good conductors

A

strong electrolytes

28
Q

are generally polar covalent substances that do not dissociate completely in water and whose solutions are poor conductors of electricity

A

weak electrolytes

29
Q

various substances that permit the passage of some molecules but not others are said to be

A

semipermeable membranes

30
Q

the more __________- present, the more effective electroconductibity

A

ions

31
Q

occur since the solvent is more concentrated on the side of the membrane containing pure water and more collisions per unit time by solvent molecules occur there, resulting in a net flow of water into the solution

A

osmosis

32
Q

the pressure exerted on the membrane due to the hydrostatic pressure on the solution forcing solvent from the solution into the pure solvent at the same rate that is flows in the reverse direction

A

osmotic pressure

33
Q

the direction of the solvent flow is always from the more ______________ solution to the more _____________ concentrated solution

A

more dilute to more concentrated

34
Q

used to desalinate water

A

reverse osmosis