Section 13.5- Reaction Mechanisms Flashcards
steps a chemical reaction goes through in order to be successful
reaction mechanism
steps which each represent a single molecular collision are called
elementary reactions
the rate-determining step is the
slowest step
the overall rate depends on the ______________________ in a series of steps
slowest step
the __________________________ cannot be used to predict either the rate or the mechanism of a reaction except in rare cases
balanced net equation
when one of the products of a reaction reacts again with something else and so on
chain reaction
3 types of steps in a chain reaction
- chain-initiating step
- chain-propagating steps
- chain-terminating steps
the rate of a chemical reaction can often be described by a ________________, an equation that relates the reaction rate to the concentrations of the reactants
rate law
equation for the rate law
rate = k[A]^x[B]^y…
in the rate law equation, the x and y exponents are usually small integers, and k is a proportionality constant called the
rate constant
the rate law depends only on the_______________________, not the stoichiometry
mechanism of the reaction
the rate law of an ELEMENTARY reaction can be determined from the reaction’s
stoichiometry