Ch 7 Section 4 Flashcards
when a new substance is synthesized or discovered, it is analyzed
quantitatively to reveal its percentage composition
from these data (percentage composition), the
empirical formula is determined
an empirical formula consists of the symbols for the elements combined in a compound, with subscripts showing
the smallest whole-number mole ratio of the different atoms in the compound
for an ionic compound, the formula unit is usually
the compound’s empirical formula
for a molecular compound, the empirical formula does not necessarily indicate the
actual numbers present in each molecule
to determine a compound’s empirical formula from its percentage composition, begin by
converting percentage composition to a mass composition
(conversion of percentage comp. to mass comp.) assume that you have a
100.0 g sample of the compound
(conversion of percentage comp. to mass comp.) then calculate the amount of each
element in the sample
next, the mass composition of each element is converted to a
composition in moles by dividing the appropriate molar mass
to find a ratio of smallest whole numbers, divide each number of moles by the
smallest number in the existing ratio
because of rounding/ experimental error, a compound’s mole ratio sometimes consists of numbers close to
whole numbers instead of exact whole numbers.
in such a case (close to whole #s instead of exact) the differences from whole numbers may be
ignored and the nearest whole number taken
sometimes mass composition is known instead of
percentage composition
to determine the empirical formula in this case (when mass comp. is known as percentage comp.) convert mass composition
to composition in moles and calculate the smallest whole-number mole ratio of atoms
the molecular formula is the actual formula of a
molecular compound