5A.2 Geometric isomersim Flashcards

1
Q

what are stereoisomers

A

they are compounds with the same structural (and molecular formula) but the atoms or group are arranged differently in three dimensions

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2
Q

what are the two types of stereoisomers

A
  1. geometric

2. optical

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3
Q

what are geometric isomers

A

they are compounds containing double carbon bonds with atoms or groups attached at different positions

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4
Q

why cant we represent geometrically isomers with a structural formula (straight line)

A

because we need to show the 120 bond angle

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5
Q

what are the two different arrangements for geometric isomers

A

trans - across

cis - same side

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6
Q

how do geometric isomers work only with alkenes

A

because alkenes have a double bond that would restrict the rotation around the double bond leaving the groups attached to the carbon double bond in one place while alkanes the groups can rotate freely

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7
Q

why can’t cis-trans naming system works

A

because 4 atoms can be attached to the carbon double bond

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8
Q

how do you use the e-z naming system

A

1,. find the mane of the compound

  1. find which atom has priority on each side of the carbon double bond (the higher the atomic number the higher the priority
  2. if the priority atom are across each other they are E-isomer if the are beside each other it is a z isomer
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