5A.2 Geometric isomersim Flashcards
what are stereoisomers
they are compounds with the same structural (and molecular formula) but the atoms or group are arranged differently in three dimensions
what are the two types of stereoisomers
- geometric
2. optical
what are geometric isomers
they are compounds containing double carbon bonds with atoms or groups attached at different positions
why cant we represent geometrically isomers with a structural formula (straight line)
because we need to show the 120 bond angle
what are the two different arrangements for geometric isomers
trans - across
cis - same side
how do geometric isomers work only with alkenes
because alkenes have a double bond that would restrict the rotation around the double bond leaving the groups attached to the carbon double bond in one place while alkanes the groups can rotate freely
why can’t cis-trans naming system works
because 4 atoms can be attached to the carbon double bond
how do you use the e-z naming system
1,. find the mane of the compound
- find which atom has priority on each side of the carbon double bond (the higher the atomic number the higher the priority
- if the priority atom are across each other they are E-isomer if the are beside each other it is a z isomer