3E.1 Introduction to solid lattices Flashcards
what are the properties of metallic lattices
- good conductor of heat and thermal energy
- they have high melting and boiling points
- malible
4, ductility
what are the properties of ionic lattices
- they have high melting
- the are soluble in water
- good conductors of electricity when dissolved in water or molten
- very brittle
what are giant covalent lattice
a giant network of atoms joined together by covalent bonds
what are the main types of gaint covalent bonds
- diamond
- graphite
- graphene
- silicon (IV) oxide
what is the boning in diamond
each carbon atom forms a sigma bond with another 4 carbon atoms forming a tetrahedral with a 109.5 angle
what are the properties of diamond
they are very strong (stong C-C bond throughout the structure) and have a high melting point because a lot of energy is required to break a great number of strong carbon-carbon bonds
what is the bonding in Graphite
each carbon forms 3 sigma bonds with 3 other carbon forming an interlocking hexagonal shape, the 4 electron is in the p orbital, and since the carbon atoms are close enough they would all overlap each other forming a sea of delocalized electrons
lubricating properties are a result
absorbed gases on the surface of the carbon atoms that’s why at high altitudes or vacumes the lubricant wouldn’t be much lowered
what are the properties of graphite
- it’s used at a lubricating (not in space thou)because its layers can easily slide over each other
- it is a good conductor of electricity as the delocalized electrons are free to flow once a potential difference is applied. graphite can only conduct electricity parallel to its layers, the delocalized electrons can flow throw all its layers allowing it to conduct electricity at all sides (unlike metals)
- high melting point (stong C-C bond throughout the structure)
what is graphene
one layer thick graphite (the same bonding)
what are the properties of molecular solids
low boiling and melting point, that is because to melt the solid you don’t have to necessarily break the covalent bonds between the atoms but the week intermolucler forces in between them making it require less energy to break than covalent bonds
how do the intermolecular forces increase
- the number of electrons per molecule
2. the length of that molecule