3C.2 Shapes of molecules and ions Flashcards
what does the electron pair repulsion theory state (VSEPR)
A molecule or an ion’s shape is caused by the repulsion of the electron(bond pairs and lone pairs) in the central shell. the electron pairs arrange themselves around the central atom to keep the repulsion between them at a minimum. lone pair-lone pair repulsion> lone pair-bonded pair repulsion> bond pair-bond pair repulsion (this determines the bond angles
how do you find the shape of molecules and ions
you do that by finding the number of bond pairs and lone pairs of electrons around the central atom (dot cross diagram)
molecules with multiple bonds
the best way to deal with it is to treat each multiple bonded as it only contains one election
what are the types of shapes molecule and form
- linear (2 bonds)
- trigonal planar (3 bonds)
- tetrahedral (4 bonds)
- trigonal bipyramidal (5 bonds)
- octahedral (6 bonds)
- trigonal pyramidal (3 bonds)
- v-shaped (2 bonds0
what angle do the linear form and an example
180 BeCl2
what angle do the trigonal planar form and an example
120 BCl3
what angle do the tetrahedral form and an example
109.5 CH4 or NH4
what angle do the trigonal bipyramidal form and an example
120 between and 90 PCl3
what angle do the octahedral form and an example
90 SF6 because the f are opposite one another
what angle do the trigonal pyramidal form and an example and why
107 NH3 because the lone pair-bond pair repulsion is stronger than the bond pair-bond pair repulsion
what angle do the V-shaped form and an example and why
104.5 H2O since the lone pair-lone pair repulsion is stronger than lone pair-bond pair repulsion it would be less than 109