Chemsitrh - Chemical Analysis Flashcards

1
Q

Colour of lithium ion flame

A

Bright red

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2
Q

Colour of sodium ion flame

A

Yellowy orange

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3
Q

Colour of potassium ion flame

A

Lilac

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4
Q

Colour of calcium ion flame

A

Brick red

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5
Q

Colour of copper ion flame

A

Blue green

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6
Q

Test with sodium hydroxide what colour precipitate is made from copper 2 ion

A

Blue precipitate

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7
Q

Test with sodium hydroxide what colour precipitate is made from iron 2 ion

A

Green precipitate

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8
Q

Test with sodium hydroxide what colour precipitate is made from iron 3 ion

A

Brown precipitate

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9
Q

Test with sodium hydroxide what colour precipitate is made from ammonium (and what other step is needed)

A
  • mixture needs to be warmed
  • no precipitate, but stinky smelling gas that turns damp red litmus paper blue
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10
Q

Test with sodium hydroxide what colour precipitate is made from aluminium ion

A

White precipitate

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11
Q

Test with sodium hydroxide what colour precipitate is made from calcium ion

A

White precipitate

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12
Q

How to tell difference between calcium and aluminium ions in sodium hydroxide?

A

Aluminium dissolves in excess whereas calcium doesn’t

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13
Q

How do you test for sulphates?

A

Mix BaCl2 with HCl
Add new acidified BaCl2 to sulphate/ unknown substance
White precipitate - barium sulphate should be formed

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14
Q

Testing for halide ions and what colours they turn

A
  • Add HNO3 to AgNO3
  • Add no more than 1cm3 of halide and then add acidified AgNO3 solution to halide
  • then silver chloride should turn white precipitate
  • silver bromide should be a cream precipitate
  • silver iodide should be a yellow precipitate
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15
Q

Testing for carbonates

A
  • add some HCl to 1cm3 of the ‘carbonate’
  • then test it by bubbling it through limewater
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16
Q

what happens when a carbonate is bubbled through limewater?

A

it turns it cloudy and makes little lumps of solid, and afterwards it should turn colourless again

17
Q

What is limewater?

A

Calcium hydroxide solution

18
Q

Why does the reaction between calcium carbonate and sulphuric acid stop effervescent after a few seconds?

A

As a protective coating of insoluble calcium sulphate is formed around the calcium carbonate - coating any remaining calcium carbonate and preventing any further reaction with sulphuric acid and hence no more calcium sulphate is formed

19
Q

Equation (with state symbols) between carbon dioxide and limewater

A

Ca(OH)2 (aq) + CO2(g) —> CaCO3 (s) + H2O (l)

20
Q

Equation for the 2nd reaction between carbon dioxide and limewater

A

CaCO3 (s) + H2O (l) + CO2 (g) —> Ca(HCO3)2 (aq)