Chem - quantitive chem!!! Flashcards
what is the atom economy?
an indication of the amount of starting material that is converted into USEFUL products
what is the equation for % atom economy
mass of desired product/ total mass of reactants * 100
what is a mole or 6.02 * 10 to the 23 also known as
Avagadros number
Relative atomic mass is the Ar in ? that contains 1 ? of atoms of that element, eg 23g of sodium will contain ? Mole of ? atoms
GRAMS, mole, 1, Na
difference between RAM and RFM
RAM is the relative atomic mass - the average atomic mass of the element/atom compared to for example a 1/12 of the mass of 12C isotope, whereas RFm is the relative formula mass of the whole compoun
Equation for mass of one atom of a substance?
m = Ar/ 6.02 *10 to the 23
equation for number of moles of a substance given the mass and RFM
moles = mass/ RFM or n =m/Mr
equation for mass given RFM and no of moles
mass = moles * RFM or m = n * Mr
what is the empirical formula of a compound?
the simplest whole number ratio of atoms present in a compound
what is meant by molecular formula?
number of atoms of each element in a molecule
equation for molecular formula?
Mr(molecule)/ Mr(empirical formula)
magnesium oxide experiment- why was the lid needed in the experiment?
to prevent any powdered MgO - which looks like smoke being lost during heating
why was the kid lifted off and replaced on the crucible in the MgO experiment
to allow a small amount of O2 to enter the crucible in order to keep burning off the Mg ribbon
why are the results in the MgO experiment not very reliable?
- very small change of mass so % error can be very large
- MgO can cost the ribbon so some Mg will never react with air
- it’s easy to lose MgO
3 steps of reacting mass calculations :
1. use mass to find the number of ? of the substance using the equation ?
2. use the balancing numbers in ? equation to find the ? of moles of the substance ? about
3. find the mass of this using the equation ?
moles, n= m/Mr, symbol, no. , asked, m = n *Mr
calculating percentage yield : 3 reasons why you may not get as much product as you would expect
- some product is lost in purification
- reaction may be incomplete
- there may be side reactions
equation for % yield?
actual yield (how much is made)/ theoretical yield ( max amount possible) * 100
how to work out concentration from mass and volume - equation
conc. = mass (in g)/ vol (in dm cubed)
what is the conversion from vol in cm3 to vol in dm3
divide cm3 by 1000
equation for conc using no of moles and volume
Conc. = number of moles/ volume
equation for conc in g/dm3
conc (g/dm3) = conc (mol/dm3) * Mr
how to work out no of moles in a gas?
n = v(in dm3)/ 24dm3
volume equation in gases
V(gas) = n * 24dm3
3 step solution to most mole questions!!!
1. find the no of ? of one of the subjects using the equations : n= m/Mr - if given a ? , n= ? if given a conc and volume, or n(gas) = ?
2. use the balancing numbers in the symbol ? to find the ? of moles asked about
3. find the asked about thing/ ? using any of about 5 equations : m= nMr, Mr = ?, V(gas) = n ?dm3, C= n/V or V(for a solution) = ?
- moles, mass, cV, v/24dm3
- equation, number
- m/n, 24, n/c