chemistryyy Flashcards

1
Q

Whose ideas did John Newlands build on on the periodic table ( in in 1864)

A

John Dalton’s

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2
Q

What idea of his did John Newlands use his periodic table to demonstrate

A

‘Law of Octaves’

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3
Q

What two things did Mendeleev do to his table that Newlands did not?

A

He left gaps in the table and predicted what the gaps would be
He also swapped the order of some of the elements

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4
Q

What two elements did Mendeleev swap round and why

A

Telerium and iodine because their atomic properties didn’t match their mass - although telerium has a higher atomic mass, iodine has a higher atomic number so he put that in front of tellurium on the periodic table

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5
Q

What similarities did Mendeleev and Newlands have with their periodic tables??

A

They both arranged it by mass

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6
Q

Why was Newland’s ideas not recognised why his peers (2 reasons)

A

Some boxes had two elements ( for no reason in particular)
He arranged it according to a piano (why?!)

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7
Q

3 important details between mendeleev’s table and the modern periodic table

A

1 - modern one is arranged by atomic number not atomic mass (mass number)
2 -modern one has no gaps, elements have been discovered
3 - in mendeleev’s table a whole group - noble gases - group 0/8 was omitted because they hadn’t been discovered yet

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8
Q

how many elements were there in mendeleev’s table compared to the modern one (roughly)

A

63, there are now 118

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9
Q

what is a group on the periodic table

A

a vertical column

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10
Q

what is a period on the periodic table

A

a horizontal row

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11
Q

what do elements in the same group have in common?

A

they have the same number of electrons in their outer shell and therefore have similar chemical properties

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12
Q

what do elements in the same period have in common?

A

they have the same number of electron shells, so therefore have similar chemical properties

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13
Q

where are the transition metals between

A

the elements in the gap between groups 2 and 3

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14
Q

what is the difference between metal and non- metal oxides

A

metal oxides are basic compounds, however non-metal oxides are acidic compounds

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15
Q

what is another name for the group 2 elements in the periodic table

A

Alkaline earth metals

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16
Q

what is another name for the group 1elements in the periodic table

A

Alkali metals

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17
Q

what is another name for the group 7 elements in the periodic table

A

halogens

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18
Q

what is another name for the group 0/8 elements in the periodic table

A

noble gases

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19
Q

make two comparisons of titanium and sulphur’s properties

A
  1. titanium is a shiny silvery metal, whereas sulphur is yellow solid (and non metal)
  2. titanium conducts electricity while sulphur does not
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20
Q

How does hardness change as you go down the group with alkali metals and why is this?

A

As you go down the group, the metals become softer and easier to cut - due to the metallic bond getting weaker

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21
Q

How does density change as you go down the group with alkali metals and why is this?

A

The elements get denser, because of the atoms of the elements increasing in size

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22
Q

which alkali metals are less dense than water

A

lithium, sodium and potassium

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23
Q

which alkali metals are denser than water

A

rubidium and caesium

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24
Q

do alkali metals have high or low boiling points?

A

low

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25
how and why does the melting point change as you go down the alkali metals
it decreases, as the metallic bonding gets bigger due to the bigger atoms
26
why do alkali metals have to be stored in oil?
because they are very reactive and otherwise would react with the oxygen and water vapour in the air
27
metals go from shiny to ? when cut ( ad in the presence of oxygen)
dull, tarnished
28
5 things happen when alkali metals react with water: 1 - they ? 2 - Li, Na and K float on the ? 3 - Na and K ? 4 - ? Rb and Cs -> flame (fire) 5 - leaves behind a very ? solution at the end - pH 14, cause by ? ion
fizz, surface, melt, K, alkaline, OH-
29
give a word equation for what happens when lithium reacts with water
lithium + water -> lithium hydroxide + hydrogen
30
what gas is given off after a reaction between an alkali metal and water
hydrogen
31
give a balanced symbol equation for a reaction between lithium and water :
2Li + 2H2O-> 2LiOH +H2
32
what happens to the reactivity of alkali metals as you go down the group and why?
they get more and more reactive, as the electron in the outer shell gets further away from the nucleus so is less attracted to it and therefore gets easier to lose
33
3 common features of alkali metal compounds ( eg NaCl )
they are white solids, they are always soluble in water, when dissolved in water they are always colourless
34
what type of molecules do elements in group 7 form
diatomic molecules
35
as you go down the halogens, what happens to the melting and boiling points??
they increase
36
what colour is fluorine as a pure element
pale yellow
37
what colour is chlorine as an element and as dissolved in water
green as pure element, and pale green in water
38
what colour is bromine as a pure element and dissolved in water
red/brown as a pure element and orange in water
39
what colour is iodine as a pure element and as dissolved in water
grey, shiny (solid) and brown in water
40
what colour is astatine as a pure element
black
41
what happens to the covalent bonds as you go down the halogens
they get weaker
42
why does the melting points of halogens get higher as you go down the group?
because as you go down the group the intermolecular forces between the (diatomic) molecules get stronger and so require more energy to break them therefore higher melting (and boiling) points
43
what type of compound is formed when a halogen reacts with a metal and what type of bonding is this
a halide, ionic bonding
44
a halide reaction is called direct ? as two ? simply combine to form a ?
combination, elements, compound
45
give a word equation for the direct combination reaction between aluminium and chlorine :
aluminium + chlorine -> aluminium chloride
46
what is it called when an element gains electrons
reduction
47
what is it called when an elements loses electrons
oxidation
48
Al has gone to Al3+, is this reduction or oxidation - and write a half equation to show this
oxidation, as Al has lost 3 electrons - Al -> Al3+ + 3e-
49
what happens to the reactivity of the halogens as you go down the group
they get less and less reactive
50
is the trend for reactivity in group 1 and group 7 the same or different, why?
different as in group 7 it works the opposite as halogens need to gain an electron so halogens at the top of the group have smaller atoms - so therefore a greater attraction to the nucleus making it easier for them to gain an electron and making them more reactive
51
What two things do displacement reactions need to take place
A halogen element - eg chlorine (Cl2) A compound of another halogen - eg sodium bromine (NaBr)
52
in displacement reactions a ? reactive halogen element will displace a ? reactive halogen from the compound
more, less
53
what causes colour change in a displacement reaction?
the leftover halogen element product
54
in a displacement reaction eg : chlorine + sodium bromide -> sodium chloride + bromine which part would cause colour change
bromine - would cause a yellow orange colour to form
55
Group 0/8 - the ? gases are all ? gases with a full ? shell of electrons
noble, unreactive, outer
56
What type of molecules/atoms do noble gases exist as
monatomic - single atoms
57
noble gases are all colourless at ? temperature and as their atomic number increases their densities and ? points also increase
room, boiling
58
how does the force of attraction between noble gas atoms change
they increase with atom size, therefore melting point increases
59
what are the forces between noble gas atoms called
van der waal forces
60
noble gases : as the ? mass increases, the boiling point also ? due to ? forces between atoms
atomic, increases, large/strong
61
what is helium used in and why
1 - balloons - low density - floats 2 - diving - can dive lower - helium insoluble in blood
62
Why is helium being insoluble in blood such a good thing
using nitrogen instead causes small bubbles in the blood can lead to bends ( a dangerous medical condition) helium does not do this !
63
what is neon used for
neon lights
64
what is argon used in??
lightbulbs - prevents filament from burning
65
what are both krypton and xenon used in..?
lasers
66
what is radon and how does it cause problems when you are in its presence
a radioactive gas, can cause cancer is a health hazard in general
67
transition metals have ? properties because as you go across the rows an ? electron shell ( the ? shell) is being filled
similar, inner, 3rd
68
the 3rd shell can hold a max of ? electrons once the 4th shell holds at least ? electrons
18, 2
69
transition metals have many typical physical properties of metals, what are they? (give 4 answers)
good conductor of electricity ductile and malleable shiny sonorous (sounds nice)
70
transition metals are ? reactive than main block ? (eg: sodium and magnesium) transition metals are also good ? meaning they can speed up a reaction without being used up
less, metals, catalysts
71
t metals also form compounds which are ?, eg copper sulphate is ? , these compounds are used as a ? when making pottery. also when in the presence of carbon dioxide and moisture ( from ?) , copper reacts to produce a ? film which is called verdigris and is found on statues eg statue of ?
coloured, blue, dye, air, green, Liberty
72
t metals can also produce more than one ?, eg: ?can only form one ion - Mg2+, while copper can form two - Cu+ and ? and iron forms ? as well - ? and Fe3+
ion, magnesium, Cu2+, two, Fe2+
73
why are iron and steel used in construction
are transition metals - very strong, malleable ductile able to be drawn into a line and made into things and are far less reactive than other metals so won't decay or react with the air as much
74
why are some saucepans made out of copper
copper is a good conductor of electricity and so it heats up the water more quickly
75
how to test for chlorine
damp blue litmus paper will turn white
76
what gas dissolves in water to form hydrochloric acid
hydrogen chloride
77
what is a redox reaction
a reaction with reduction and oxidation in it - a reaction where electrons are lost and gained!!