Wrong Pile. Flashcards
What is pitch related to in sound?
Pitch is related to frequency.
Relate K and G
Delta G = - RT lnk.
Therefore, if K is greater than one then the delta g is negative.
What is usually the first step of a acid catalyzed reaction for carbonyls?
Typically, the acid protonates the double bonded oxygen of the carbonyl. The protonation allows the formation of a resonance structure where the carbonyl carbon has a positive charge and is susceptible to attack.
What is the formula to calculate percent error?
experimental - theoretical / theoretical
On a heating curve, when is the average kinetic energy not changing?
Remember the temperature stays the same during a phase shift. The average kinetic energy will remain the same during a change in phase.
What is the IR Spectrum for OH?
Broad peak around 3000 to 3700.
What is a constitutional isomer?
Two compounds have the same formula, but different connectivity.
What does the Benedict’s solution test positive for?
It tests positive for aldehyde and alpha- hydroxyketones sugars.
What are alpha hydroxyketones?
A ketone where the exterior carbon has a hydroxyl group attached.
How is the mass of an object effected when you move it to another planet?
The mass is not effected.
What is acetic acid?
lone Carboxylic Acid (ketone)
What is formic acid?
Lone Carboxylic Acid (aldehyde)
Relate specific gravity, density, and buoyant force.
If the density is big, then the specific gravity is bigger, therefore the buoyant force is higher because the density is high.
What is nitrate?
NO3-
What is Carbonate?
CO3^2-
How does competitive inhibition affect the sigmoidal graph? Not line weaver.
Rightward shift with same vMax.
How does a noncompetitive inhibitor affect the sigmoidal graph? Not line weaver.
Decreased VMax level.
If you were to replace one element with another and attempt to exhibit then same effects, then which atom would you most likely choose?
The replacement atom should be in the same group because they have the same characteristics.
What is the definition of a carbohydrate
Must have the formula: CH2O, but must also have more than 2 carbon atoms.
Is combustion exothermic or endothermic?
Combustion gives off energy and heat so it is exothermic.
What is H2SO3?
Sulfurous acid
What is the carbonyl region of IR?
Around 1700-1800
How do you calculate the heat of vaporization for water given an enthalpy table?
Vaporization is liquid to gas.
Use products - reactants with the enthalpy values.
What is the explanation for why light travels slower through an optically dense medium.
The light is absorbed and re-emitted by the atomic structure of the optically sense medium.
What is a sulfonyl group?
Sulfur with at least two double bonded oxygens attached.
What is a urea group?
Carbonyl oxygen, carbon attached to two amine groups.
Relate adding volume to concentration & pH
pH is calculated by the -log(h) concentration. If the M is the same after adding a volume, then the pH must not change.
Solution chemistry tells us that if concentration remains the same, then volume changes will not affect pH.
What is Poiseuille’s Law for flow rate and what is the implication?
Flow = ΔPπr^4 / 8Lη.
Big take away from this equation is r^4. Changing the radius SIGNIFICANTLY changes the changes the flow rate.
What are the different formulas for power?
Power = work (fd) / time. Power = force (time) Power = Kinetic energy(.5mv^2) / time.
What is the area under/ in the PV graph?
Work.
What are the characteristics of a good nucleophile?
A good nucleophile must have lots of electrons to donate. Also, the nucleophile must not be sterically hindered.
What is the relative reactivity of carbonyl groups?
The relative reactivity is:
Acyl Halides > Anhydrides > Esters & Acids > Amides
What do amino groups do in term of polarity?
Amines make the molecule more polar.
Describe DNA Methylation, DNA Acetylation, and DNA Deacetylation.
DNA Methylation blocks transcription by closing histones.
DNA Acetylation increases transcription by opening histones.
DNA Deacetylation blocks transcription by removing acetyl groups.
Contrast Mass spec and gas chromatography:
Mass spectrometry is used to measure the size of one molecule and would not be useful to carry out a separation of two molecules
Gas chromatography separates molecules based on affinity
What is another name of humoral immunity?
Adaptive immunity