Chemistry Chapter 8: The Gas Phase (3 Stars) Flashcards

1
Q

______ are the least dense phase of matter.

A

Gases

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2
Q

Gases are _____ and therefore conform to the shapes of their containers.

A

fluids

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3
Q

Gases are easily ______

A

compressible.

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4
Q

Gas systems are described by the variables temperature (T), pressure (P), ______, and number of moles (n).

A

volume (V)

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5
Q

Important pressure equivalencies include 1 atm = 760 mmHg ≡ 760 ____ = 101.325 kPa.

A

torr

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6
Q

A simple mercury barometer measures incident (usually atmospheric) pressure. As pressure increases, _____ mercury is forced into the column, increasing its height. As pressure decreases, mercury flows out of the column under its own weight, decreasing its height. Ideal Gases

A

more

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7
Q

Standard temperature and pressure (STP) is ____ K (0°C) and 1 atm.

A

273 K

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8
Q

Equations for ideal gases assume negligible ___ and volume of gas molecules.

A

mass

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9
Q

Regardless of the identity of the gas, equimolar amounts of ____ gases will occupy the same volume at the same temperature and pressure. At STP, one mole of an ideal gas occupies 22.4 L.

A

two

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10
Q

The ideal gas law describes the relationship between the ___ variables of the gas state for an ideal gas.

A

four

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11
Q

Avogadro’s principle is a special case of the ideal gas law for which the pressure and temperature are held ____; it shows a direct relationship between the number of moles of gas and volume.

A

constant

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12
Q

Boyle’s law is a special case of the ideal gas law for which temperature and number of moles are held constant; it shows an _____ relationship between pressure and volume.

A

inverse

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13
Q

Charles’s law is a special case of the ideal gas law for which pressure and number of moles are held constant; it shows a direct relationship between _____ and volume.

A

temperature

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14
Q

Gay-Lussac’s law is a special case of the ideal gas law for which volume and number of moles are held constant; it shows a direct relationship between temperature and _____

A

pressure.

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15
Q

The combined gas law is a combination of Boyle’s, Charles’s, and Gay-Lussac’s laws; it shows ____ relationship between pressure and volume along with direct relationships between pressure and volume with temperature.

A

inverse

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16
Q

Dalton’s law of ____ pressures states that individual gas components of a mixture of gases will exert individual pressures in proportion to their mole fractions. The total pressure of a mixture of gases is equal to the sum of the partial pressures of the component gases.

A

partial

17
Q

Henry’s law states that the amount of gas dissolved in solution is directly proportional to the _______of that gas at the surface of a solution.

A

partial pressure

18
Q

The kinetic molecular theory attempts to explain the behavior of ___ particles.

A

gas

19
Q

Gas particles have negligible _____

A

volume.

20
Q

Gas particles do not have _____ attractions or repulsions.

A

intermolecular

21
Q

Gas particles undergo ____ collisions with each other and the walls of the container.

A

random

22
Q

Collisions between gas particles (and with the walls of the container) are _____

A

elastic.

23
Q

The average kinetic energy of the gas particles is directly _____ to temperature.

A

proportional

24
Q

Graham’s law describes the behavior of gas diffusion or effusion, stating that gases with lower molar masses will diffuse or effuse ____ than gases with higher molar masses at the same temperature.

A

faster

25
Q

Diffusion is the spreading out of particles from ____ to ___concentration.

A

high to low

26
Q

_______ is the movement of gas from one compartment to another through a small opening under pressure.

A

Effusion

27
Q

Real gases deviate from ideal behavior under ____ pressure (low volume) and low temperature conditions.

A

high

28
Q

At moderately high pressures, low volumes, or low temperatures, real gases will occupy ____ volume than predicted by the ideal gas law because the particles have intermolecular attractions.

A

less

29
Q

At extremely high pressures, low volumes, or low temperatures, real gases will occupy more volume than predicted by the ideal gas law because the particles occupy ______

A

physical space.

30
Q

The van der Waals equation of state is used to correct the ideal gas law for intermolecular attractions (a) and ______

A

molecular volume (b).

31
Q

What is the equation for ideal gas law?

A

PV = nRT