Chemistry Chapter 8: The Gas Phase (3 Stars) Flashcards

1
Q

______ are the least dense phase of matter.

A

Gases

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2
Q

Gases are _____ and therefore conform to the shapes of their containers.

A

fluids

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3
Q

Gases are easily ______

A

compressible.

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4
Q

Gas systems are described by the variables temperature (T), pressure (P), ______, and number of moles (n).

A

volume (V)

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5
Q

Important pressure equivalencies include 1 atm = 760 mmHg ≡ 760 ____ = 101.325 kPa.

A

torr

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6
Q

A simple mercury barometer measures incident (usually atmospheric) pressure. As pressure increases, _____ mercury is forced into the column, increasing its height. As pressure decreases, mercury flows out of the column under its own weight, decreasing its height. Ideal Gases

A

more

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7
Q

Standard temperature and pressure (STP) is ____ K (0°C) and 1 atm.

A

273 K

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8
Q

Equations for ideal gases assume negligible ___ and volume of gas molecules.

A

mass

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9
Q

Regardless of the identity of the gas, equimolar amounts of ____ gases will occupy the same volume at the same temperature and pressure. At STP, one mole of an ideal gas occupies 22.4 L.

A

two

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10
Q

The ideal gas law describes the relationship between the ___ variables of the gas state for an ideal gas.

A

four

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11
Q

Avogadro’s principle is a special case of the ideal gas law for which the pressure and temperature are held ____; it shows a direct relationship between the number of moles of gas and volume.

A

constant

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12
Q

Boyle’s law is a special case of the ideal gas law for which temperature and number of moles are held constant; it shows an _____ relationship between pressure and volume.

A

inverse

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13
Q

Charles’s law is a special case of the ideal gas law for which pressure and number of moles are held constant; it shows a direct relationship between _____ and volume.

A

temperature

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14
Q

Gay-Lussac’s law is a special case of the ideal gas law for which volume and number of moles are held constant; it shows a direct relationship between temperature and _____

A

pressure.

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15
Q

The combined gas law is a combination of Boyle’s, Charles’s, and Gay-Lussac’s laws; it shows ____ relationship between pressure and volume along with direct relationships between pressure and volume with temperature.

A

inverse

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16
Q

Dalton’s law of ____ pressures states that individual gas components of a mixture of gases will exert individual pressures in proportion to their mole fractions. The total pressure of a mixture of gases is equal to the sum of the partial pressures of the component gases.

17
Q

Henry’s law states that the amount of gas dissolved in solution is directly proportional to the _______of that gas at the surface of a solution.

A

partial pressure

18
Q

The kinetic molecular theory attempts to explain the behavior of ___ particles.

19
Q

Gas particles have negligible _____

20
Q

Gas particles do not have _____ attractions or repulsions.

A

intermolecular

21
Q

Gas particles undergo ____ collisions with each other and the walls of the container.

22
Q

Collisions between gas particles (and with the walls of the container) are _____

23
Q

The average kinetic energy of the gas particles is directly _____ to temperature.

A

proportional

24
Q

Graham’s law describes the behavior of gas diffusion or effusion, stating that gases with lower molar masses will diffuse or effuse ____ than gases with higher molar masses at the same temperature.

25
Diffusion is the spreading out of particles from ____ to \_\_\_concentration.
high to low
26
\_\_\_\_\_\_\_ is the movement of gas from one compartment to another through a small opening under pressure.
Effusion
27
Real gases deviate from ideal behavior under ____ pressure (low volume) and low temperature conditions.
high
28
At moderately high pressures, low volumes, or low temperatures, real gases will occupy ____ volume than predicted by the ideal gas law because the particles have intermolecular attractions.
less
29
At extremely high pressures, low volumes, or low temperatures, real gases will occupy more volume than predicted by the ideal gas law because the particles occupy \_\_\_\_\_\_
physical space.
30
The van der Waals equation of state is used to correct the ideal gas law for intermolecular attractions (a) and \_\_\_\_\_\_
molecular volume (b).
31
What is the equation for ideal gas law?
PV = nRT