Chemistry Chapter 11: Oxidation-Reduction Reactions (2 Stars) Flashcards

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1
Q

______ is a loss of electrons, and _____ is a gain of electrons; the two are paired together in what is known as an oxidation–reduction (redox) reaction.

A

Oxidation

reduction

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2
Q

An ______ agent facilitates the oxidation of another compound and is reduced itself in the process; a reducing agent facilitates the reduction of another compound and is itself oxidized in the process.

A

oxidizing

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3
Q

Common oxidizing agents almost all contain _____ or a similarly electronegative element.

A

oxygen

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4
Q

Common reducing agents often contain _____ ions or hydrides (H– ).

A

metal

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5
Q

To assign oxidation numbers, one must know the common oxidation _____ of the representative elements.

A

states

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6
Q

Any free element or diatomic species has an oxidation number of _____

A

zero.

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7
Q

The oxidation number of a monatomic ion is equal to the _____ of the ion.

A

charge

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8
Q

When in compounds, Group IA metals have an oxidation number of #____; Group IIA metals have an oxidation number of #____.

A

+1

+2.

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9
Q

When in compounds, Group VIIA elements have an oxidation number of #____ (unless combined with an element with higher electronegativity).

A

-1

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10
Q

The oxidation state of hydrogen is #___ unless it is paired with a less electronegative element, in which case it is –1.

A

+1

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11
Q

The oxidation state of oxygen is usually #___, except in peroxides (when its charge is –1) or in compounds with more electronegative elements.

A

-2

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12
Q

The sum of the oxidation numbers of all the atoms present in a compound is equal to the overall ___ of that compound.

A

charge

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13
Q

When balancing redox reactions, the half-reaction method, also called the ______ , is the most common.

A

ion–electron method,

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14
Q

Separate the #____ half-reactions.

A

two

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15
Q

Balance the atoms of each half-reaction. Start with all the elements besides __ and ___. In acidic solution, balance H and O using water and H+ . In basic solution, balance H and O using water and OH– .

A

H and O

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16
Q

Balance the charges of each half-reaction by ____ electrons as necessary to one side of the reaction.

A

adding

17
Q

____ the half-reactions as necessary to obtain the same number of electrons in both half-reactions. GeneralChem_2016.indb 386 4/13/16 3:11 PM 11: Oxidation–Reduction Reactions 387

A

Multiply

18
Q

___ the half-reactions, canceling out terms on both sides of the reaction arrow.

A

Add

19
Q

Confirm that the ____ and charge are balanced.

A

mass

20
Q

A ____ ionic equation accounts for all of the ions present in a reaction. To write a complete ionic reaction, split all aqueous compounds into their relevant ions. Keep solid salts intact.

A

complete

21
Q

Net ionic equations ignore ______ to focus only on the species that actually participate in the reaction. To obtain a net ionic reaction, subtract the ions appearing on both sides of the reaction, which are called spectator ions.

A

spectator ions

22
Q

For reactions that contain no _____ salts, the net ionic equation is generally the same as the overall balanced reaction.

A

aqueous salts

23
Q

For double displacement (metathesis) reactions that do not form a solid salt, there is no net ionic reaction because all ions remain in solution and do/ do not change oxidation number.

A

do not

24
Q

________ reactions are a type of redox reaction in which one element is both oxidized and reduced, forming at least two molecules containing the element with different oxidation states.

A

Disproportionation (dismutation)

25
Q

Oxidation–reduction titrations are similar in methodology to acid–base titrations. These titrations follow ______ of charge.

A

transfer

26
Q

_______ used in such titrations change color when certain voltages of solutions are achieved.

A

Indicators

27
Q

_______ titration is a form of redox titration in which a voltmeter or external cell measures the electromotive force (emf) of a solution. No indicator is used, and the equivalence point is determined by a sharp change in voltage

A

Potentiometric