Chemical Analysis Flashcards

1
Q

What colour flame does lithium produce?

A

Crimson

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2
Q

A crimson flame means which element?

A

lithium

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3
Q

A lilac flame means which element?

A

potassium

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4
Q

An orangered / brick red flame means which element?

A

calcium

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5
Q

A yellow flame means which element?

A

sodium

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6
Q

A green flame means which element?

A

copper

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7
Q

what colour flame does potassium produce?

A

lilac

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8
Q

what colour flame does copper produce?

A

green

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9
Q

what colour flame does sodium produce?

A

yellow

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10
Q

what colour flame does calcium produce?

A

crimson

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11
Q

which metals give a white precipitate when a hydroxide is added?

A

aluminium, calcium and magnesium

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12
Q

which metal gives a green precipitate when a hydroxide is added?

A

iron 2

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13
Q

which metal gives a blue precipitate when a hydroxide is added?

A

copper 2

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14
Q

which metal gives a brown precipitate when a hydroxide is added?

A

iron 3

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15
Q

what colour precipitate is produced when hydroxide is added to aluminium?

A

white

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16
Q

what colour precipitate is produced when hydroxide is added to copper 2?

17
Q

what colour precipitate is produced when hydroxide is added to calcium?

18
Q

what colour precipitate is produced when hydroxide is added to magnesium?

19
Q

what colour precipitate is produced when hydroxide is added to iron 2?

20
Q

what colour precipitate is produced when hydroxide is added to iron 3?

21
Q

How do you distinguish between aluminium, calcium and magnesium

A

AlOH precipitate dissolves to form a colourless solution when more NaOH is added
MgOH and CaOH remain unchanged

22
Q

How do you test for a carbonate ion?

A

acid (usually dilute HCl but any works) added to test compound
CO2 bubbles
limewater test

23
Q

how do you test for copper?

A

green flame
blue precipitate when hydroxide added

24
Q

how do you test for calcium?

A

crimson flame
white precipitate when hydroxide added

25
how do you test for aluminium?
white precipitate when hydroxide added. when more is added it dissolves to form a colourless solution
26
how do you test for iron 2?
green precipitate when hydroxide added
27
how do you test for iron 3?
brown precipitate when hydroxide added
28
how do you test for sulfate ions?
barium ions react with sulfate ions to form white precipitate: add a few drops of dilute HCL add a few drops of dilute BaCl
29
how do you test for halide ions?
add silver nitrate
30
which halide ion produces white ppt when silver is added?
chloride
31
which halide ion produces cream ppt when bromide is added?
bromide
32
which halide ion produces yellow ppt when silver is added?
iodide
33
what colour ppt is produced when silver nitrate is added to bromide?
cream
34
what colour ppt is produced when silver nitrate is added to iodide?
yellow
35
what colour ppt is produced when silver nitrate is added to chloride?
white
36
what are the problems with simple tests?
not very sensitive subjective-> false positives can't cope w/ mixtures not quantitative slow, one at a time
37
give an example of an instrumental method for chemical analysis
flame emission spectroscopy- uses a prism to split wavelengths from a flame each element has a unique series of wavelengths
38
what are the advantages of instrumental methods?
can do dilute solutions and mixtures objective; is there or not v. sensitive quantitative can be automated
39
disadvantages of instrumental methods?
expensieve, needs calibration, needs training