States if matter and the KMS study guide Flashcards

1
Q

The phase of a substance is dependent on…

A

its energy

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2
Q

The KMT of matter is based on…

A

the idea that partciles of matter are always in motion

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3
Q

Solids have a…

A

constant volume and shape
-particles are held in rigid, crystalline structure

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4
Q

Liquids have a..

A

constant volume but changing shape
-particles are mobile but still held together by strong attraction

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5
Q

Gases have…

A

no set volume or shape
-particles have broken free of forces holding them toegtehr

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6
Q

Attractive forces between particles are greatest in…

A

solids

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7
Q

Attractive forces between particles are weakest in…

A

gases

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8
Q

The KMT of Gases postulates (5):

A

-Continuous random motion
-elastic collisions
-temp of gas directly proportional to average KE of particles
-no forces of attraction btwn particle s
-no volume compared to distance betwn them (0 volume)

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9
Q

(KMT of gases) What causes an increase in collisions:

A

-more particles added
-increase in temp
-gases expand to fill containers (same shape/voluem)
-gases are fluids
-pressure exetred when partciles hit sides

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10
Q

The KMT of gases applies to…

A

ideal gases

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11
Q

(KMT of gas) Diffusion:

A

the spontaneous mixture of the particles of 2 subtances caused by random motion

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12
Q

(KMT of gas) Effusion:

A

process of gas particles passing through tiny opening

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13
Q

(KMT of liquid) Fluid:

A

substance that can flow and takes shape of container

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14
Q

(KMT of liquids) Liquids are a form of matter that has…

A

definite volume and changing shape

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15
Q

liquids also diffuse but…

A

much slower than gases. (they can move.diffuse throughout and other liquid that it cna dissolve in)

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16
Q

(KMT of solids) particles of solids are reflected in the…

A

orderly arrangement of solid particles

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17
Q

(KMT of Solids) the intermolecular forces attraction are much…

A

stronger than liwuids or gas and solids have lowest amnt of KE

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18
Q

(KMT of solids) Two types of solids:

A

1.Crystalline
2. Amorphous

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19
Q

Density:

A

solids are more closely packed together than liqudis or gases (higher)

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20
Q

Compressibility:

A

solids are incompressible

21
Q

Fluidity:

A

solid particles vibrate around a fixed position and do NOT flow

22
Q

Crystalline:

A

ionic crystal lattice consisting of + and - ions arranged in a repeating pattern

23
Q

Amorphous:

A

(w/o shape) particles are not arranged in a particular order

24
Q

Phase:

A

part of a system that has uniform composition and prop. (solid,liquid, gas)

25
Condensation:
gas changes to a liquid
26
Vapor:
a gas in contact w/ its liquid or solid phase
27
Equilibrium:
a condition which two opposing changes occur at equal rates in a closed system
28
Equilibrium of vapor is affected by:
concentration temp pressure
29
Because the forces of attraction are diff for diff liquids, the equilibrium vapor pressure is..
specific for each liquid at a given temp
30
Volatile liquids:
liquids that evaporate easily due to very weak forces of attraction
31
NONvolatile liquids:
liquids that do Not evaporate easilt -- strong forces of attraction
32
Energy is always involved when:
a physical/chemical change occurs
33
Change of state is a:
physical change
34
Liquid to gas:
vaporization (endo)
35
Gas to liquid:
Condensation (exo)
36
Solid to Liquid:
melting (endo)
37
liquid to solid:
Freezing (exo)
38
solid to gas :
sublimation (endo)
39
Boiling:
the changes of a liquid to a vapor within the liquid and at its surface
40
Boiling point:
the temp at which the equilibrium vapor pressure of liquid euals the atmospheric pressure (surroundings)
41
Lower atmospheric pressure =
lower boiling point
42
The heating curve plots the change in...
temp of a substance as it changes from a solid to a liquid to gas
43
During phase change, KE is used to...
break attractive forces btwn particles
44
Triple point:
point at which all 3 phases of matter are in equilibrium --exist at same time
45
Critical point:
the critical pressure and temp for the substance
46
Critical temp:
the temp above which substance cannot exist as a liquid
47
Critical pressure:
the lowest pressure at which the substance, at critical temp, can exist as a liquid
48
Heat of fusion:
q=mHf (334 J/g)
49
Heat of vaporization:
q=mHv ( 2260 J/g)