MIDTERM STUDY (unit 4/5 Flashcards

1
Q

Only s and p orbitals are

A

Valence electrons

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2
Q

Valence electrons:

A

e- in outer most energy level

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3
Q

s sublevel:

A

2 e- and Sphere shape

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4
Q

p sublevel:

A

6 e- and dumbbell shape

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5
Q

Principles that govern electron configuration:

A
  • Pauli Exclusion Principle
  • Hund’s Rule
  • Aufbau Principle
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6
Q

Pauli Exclusion Principle:

A

2 e- in same orbital must have opp spins

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7
Q

Hunds Rule:

A

e- in same sublevels occupy empty orbitals before they pair up

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8
Q

Aufbau principle:

A

e- occupy positions of lowest energy level first

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9
Q

Orbital Notation:

A

shows all e- in energy level order, with e- pairing, and opp spins

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10
Q

Lewis Dot Notation:

A

shows only valence e-

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11
Q

Bohr Model Diagram:

A

shows all e- per energy level (does not delineate between sublevels)

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12
Q

Electron Configuration:

A

use of superscripts to show the # of electrons per sublevel

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13
Q

Nobel Gas Configuration:

A

use of Nobal Gas from the period above, then show configuration of e- after that noble gas

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14
Q

Isoelectronic:

A

atoms of two different elements with the same # of e-

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15
Q

Dimitri Mendeleev:

A

developed periodic table of known elements and arranged them in order of increasing atomic mass and later ordered according to chemical properties

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16
Q

What did Mendeleev predict about the empty spaces in his periodic table:

A

they were undiscovered elements

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17
Q

What was the problem with Mendeleev’s new periodic table:

A

When elements were arranged according to similar properties, some had to be placed out of order of atomic mass

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18
Q

Henry Moseley:

A

ordered elements by atomic number (# of p+)

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19
Q

Periodic Law:

A

states that the physical and chemical properties of elements are periodic functions of their atomic #’s

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20
Q

Periodic groups;

A

(18) Elements of the same group have same valence configuration, valence electrons, and similar chemical properties

21
Q

Periodic Periods:

A

(7) elements of same period have the sma e# of occupied energy levels

22
Q

The number of valence electrons in MAIN GROUP ELEMENTS is = to

A

its group # or group number minus 10

23
Q

What are the three classes of elements:

A

Metals, Nonmetals, Metalloids

24
Q

How are elements arranged:

A

in order of increasing atomic # (# of protons) NOT MASS

25
Q

Properties of metals:

A

-easily oxidized (lose e-)
- good electrical conductors
-shiny, malleable, ductile
- low ionization energies
-low electronegativities

26
Q

Properties of Nonmetals:

A

-gain e- (are reduced)
-not conductors
- dull,brittle
-high ionization energies
- high electronegativity

27
Q

(4 types) Metals:

A

Alkali Metals
Alkaline Earth Metals
Transition Metals
Inner transition metals

28
Q

(2 types) NonMetals:

A

Halogens
Noble Gases

29
Q

Alkali Metals:

A

have 1 valence e-
NEVER found in pure form bc too reactive
Reactivity increases down group
Most reactive group of metals
soft and silvery in color

30
Q

Alkaline Earth Metals:

A

have 2 valence e-
less reactive
not found in pure form
“Basic”

31
Q

Transition Metals:

A

d/block elements

32
Q

Inner Transition Metals:

A

lanthanides and actinides

33
Q

(3 things) Halogens:

A

have 7 valence e-
most reactive group of NONMETALS
ONLY found in pure form as diatomic element

34
Q

(4 things ) Noble Gases:

A

8 valence e-
chemically unreactive
only found in pure form in nature
colorless and odorless

35
Q

Atomic Radius:

A

Left to right # of energy levels stay the same and # of protons increases in nucleus so it increases the positive nuclear charge - pulls the electrons in closer

36
Q

Atomic Radii:

A

one half the distance between the nuclei of identical atoms that are bonded together

37
Q

Ionization energy def:

A

energy required to remove one electron from an atom

38
Q

Ionization energy:

A

-As atomic radius decreases across the period, valence e- being removed is closer to positive nucleus so harder to remove and need more energy

39
Q

Electronegativity def:

A

a measure of the ability of an atom in a chemical compound to attract e- from another atom

40
Q

Electronegativity:

A

as atomic radius decreases across period, the positive nuclear charge increases making the atom’s ability to “pull in” e- much greater

41
Q

Ionic Radius:

A

Metals- decreases
nonmetals- increases

42
Q

Metals:

A

valence e- are lost to create cations

43
Q

Nonmetals:

A

Valence e- are gained to create anions

44
Q

Period Trends:

A

(across the period) affected by increasing nuclear charge, an increasing number of p+ but same number of energy levels.

45
Q

Group Trends:

A

(down the group) affected by shielding. shielding increases down the group due to increasing # of energy levels

46
Q

Shielding:

A

inner levels of e- repel the outer (valence) e- blocking the nuclear effect on the e-

47
Q

How many naturally occurring elements are there?

A

92

48
Q

Periodic Families (groups):

A

Alkali metals
alkaline earth metals
transition metals
Halogens
Noble Gases
Lanthanides (inner transition metals)
Actinides ( inner transition metals)