Polarity and IMF Flashcards

1
Q

Intermolecular forces:

A

between molecules

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2
Q

Intramolecular forces:

A

covalent bonds btwn atoms

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3
Q

Which one is stringer inter or intramolecular forces?

A

Intra

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4
Q

Molecular polarity:

A

polar bonds are formed when there is an unequal sharing of e- btwn atoms

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5
Q

Molecular polarity of molecules influences the…

A

forces btwn molecules

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6
Q

Why is it important to know the polarity of a molecule?

A

properties of subtances (boiling point and solubility) are affected by the forces btwn the molecules of a substance

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7
Q

Dipoles:

A

polar molecules

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8
Q

Dipole moment:

A

arrow used to show the direction of polarity and points towards more electronegative atom (tail crossed on the more + end)

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9
Q

Nonpolar molecules do not…

A

create poles bc equal sharing of e-

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10
Q

Polar molecules are :

A

asymmetrical

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11
Q

Nonpolar molecules are;

A

symmetrical

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12
Q

In a nonpolar molecule the forces….

A

cancel out and net dipole moment is zero

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13
Q

Molecular polarity depends on:

A

-polarity of the bonds
-the shape of the molecule

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14
Q

Determining molecular polarity:

A
  • draw lewis structure of molecule
  • determine polarity of the bonds
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15
Q

two or more lines of symmetry in molecule=

A

nonpolar

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16
Q

zero or one line of symmetry=

A

polar

17
Q

Molecular polarity is determined by:

A

shape and distribution of charge in the molecule

18
Q

SNAP:

A

Aymmetrical Nonpolar Asymmetrical Polar

19
Q

If atoms in the molecule are symmetrical=

A

charges are balanced by each other (nonpolar)

20
Q

Intermolecular forces together are called:

A

Van der Waals Forces

21
Q

Van der Waals Forces:

A

-London Dispersion Forces
-Dipole-Dipole Force
-Hydrogen Bond

22
Q

The boiling point of a liquid is determine by the…

A

strength of its intermolecular forces

23
Q

Stronger intermolecular forces=

A

higher boiling point

24
Q

Intermolecular forces vary in strength and are weaker than

A

covalent intramolecular forces

25
Q

Intermolecular forces : weakest to strongest

A

London Dispersion Forces
Dipole-Dipole force
Hydrogen Bond

26
Q

(London Dispersion Forces) E- are in

A

constant motion and distribution may be uneven

27
Q

(London Dispersion forces) uneven e- distribution creates a…

A

temporary + and - pole

28
Q

(london dispersion force) Temporary dipole can->

A

induce a dipole in a nearby atom

29
Q

London Dispersion forces:

A

intermolecular forces created by the constant motion of e- and temporary dipoles

30
Q

(london dispersion forces) Induced dipoles account for the fact that a nonpolar molecule like oxygen is able to ->

A

dissolve in water - a polar molecule

31
Q

Dipole-Dipole forces:

A

the force of attraction between polar molecules (dipole and dipole)

32
Q

Dipole-dipole forces are _____ than London Dispersion forces

A

stronger

33
Q

Hydrogen bond:

A

a special type of dipole- dipole force

34
Q

(hydrogen bond) Special type of dipole- dipole force occurs when:

A

hydrogen bonds with N,O, or F

35
Q

The strength of the hydrogen increases w/:

A

the degree of electronegativity of the atom bonded to it