carbohydrates Flashcards

1
Q

functions of carbohydrates

A

energy source
storage
structural
interellular communication

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2
Q

ring structures of larger monoshaccaries

A

pyranoses -6

furanoses - 5

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3
Q

smaller monosaccharides

A

aldoses

ketoses

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4
Q

why are ring structures formed on the larger monosaccashrides

A

oxygen on the anomeric carbon

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5
Q

what can carbohydrates form

A

D and L isomers

D in life

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6
Q

what conformation do carbohydrates form

A

chair confomration

2 anomie’s due to OH orientation on anomeritc carbon

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7
Q

bond between monomers

A

glycosidic

either alpha or beta depending on anomer

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8
Q

substitute sugars

A

carbohydrate with other groups

e.g. protein, lipid, acetyl

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9
Q

glycosaminoglycnas

A

lots of charge leading to repulsion

component of ECM

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10
Q

types of polysaccarides

A

homopolysaccarides
heteropolysaccarides

linear or branched

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11
Q

cellulose

A

glucose beta glycosidic bonds
straight chains due to B
H bonding between polymer chains

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12
Q

chitin

A

contains amine group increasing charge therefore stronger bonds
exoskeletons and cell wall of fungi/algae

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13
Q

starch

A

food reserve in plants

insoluble granules in cytoplasm

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14
Q

starch forms

A
a-amylose
linear homopolysaccaride 
glucose via alpha
helical formation (kinked)
amylopecitn
glucose monomers alpha 1-4/1-6 linakgaes
branching
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15
Q

glycogen

A

similar to amylopectin but more compact and branched

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16
Q

glycogen synthesis

A

glucose binds to UDP
glycogenin creates glucose primer using UDP glucose molecules
allows binding to aa on glycogenin
glycogen synthase sticks another UDP glucose on
repeat to make chain
branching enzyme moves glucose molecules to another glycosidic bonding, branching

17
Q

glycogen degreatation

A

glycogen phosphorylase removes glucose at ends

debranching enzyme acts as transferase, removes glucose near branch point

18
Q

glycoproteins/oligosaccharies

A

carbohydrate chains linked to protein

often branched and found on cell surface (signalling)

19
Q

how can carbohydrate groups be linked

A

N/O glycans
N linked glycosylation
spread through whole protein, effects on protein folding activity
O linked glycosaltion
occurs in clusters on specific proteins with protective role

20
Q

salivary mucin

A

O links

2-7 sugars attachede

21
Q

glycolipdis

A

act as self signals/regognition factors , intercellular commincation
feature of bacterial cell wall - different to human lipopolysaccharide

22
Q

glyco RNA

A

sugar attached to RNA

23
Q

digestion of carbohydrtaes

A

A malaise breaks 1-4 links in starch
polysaccharides to oligosaccarhres
pancreatic applause and other glycosides digest

24
Q

what happens to sugars that cannot be digested

A

fermented in the colon

25
Q

carbohydrates and oral health

A

glycolipids can be used as a food source for bacteia

bacteria can attach to structures by using glycoprotiens

26
Q

glycocalyx

A

glycoprotien and glycolipid
protective barrier between cell and outside
bacteria can produce this to stick to and form plaque