AP Bio Exam 2 Flashcards
Metabolism
The entirety of an organisms chemical reactions
Metabolic Pathway
Starting molecule (A) -> Reaction 1 -> B …. -> D (product)
Each reaction in a metabolic pathway is catalyzed by an
enzyme
Catabolic
Releasing energy by breaking down complex molecules into simplier compounds
Anabolic
Consumes energy to build complex molecules from simpler ones
Biggest example of a catabolic pathway
Cellular respiration
(Sugar glucose and organic fuels are broken down in the presence of oxygen to carbon dioxide and water)
Examples of anabolic pathways
synthesis of an amino acid from simpler molecules and synthesis of a protein from amino acids
Energy
The ability to do work
Kinetic energy
Energy of motion
Thermal energy
Kinetic energy of random movement of atoms or molecules
Heat
Thermal energy transfer from one object to another
Light Energy
Harnessed in photosynthesis to perform work
Potential energy
Energy possessed given a location or structure
Chemical Energy
The potential energy available for release in a chemical reaction
Recalling that catabolic pathways release energy from breaking down complex molecule, glucose is
high in chemical energy
Thermodynamics
Study of energy transformations
Isolated system
Unable to exchange either energy or matter with its surroundings as a opposed to open systems
Are organisms isolated or open systems?
Open: they absorb energy (light, chemical) and release energy (heat, metabolic waste)
First Law of Thermodynamics (Principle of Conservation of Energy)
Energy can be transferred and transformed, but it cannot be created or destroyed
Second Law of Thermodynamics
Every energy transfer or transformation increases the entropy of the universe
Every time an energy transfer occurs
the universe becomes more disordered
Entropy
A measure of molecular disorder or randomness
The more randomly arranged a collection of matter is
The greater the entropy
Spontaneous Reaction
A process that leads to an increase of entropy, thus can proceed without requiring an input of energy
Spontaneous =
energetically favorable (NOT will occur rapidly)
Examples of spontaneous reactions
explosions, rusting
Nonspontaneous
A process that leads to a decrease in entropy. requires energy
Water flowing downhill is ________
Water flowing uphill is ________
spontaneous
non-spontaneous
The universe is really just
the system + the surroundings
Free energy (G)
The portion of a system’s energy that can perform work when temperature and pressure are uniform throughout the system
Equation for the change in free energy
ΔG = ΔH - TΔS
ΔH
Change in Enthalpy (total energy)
ΔS
Change in entropy
T
Absolute temperature (in units K)
-ΔG
Spontaneous
(Gives up enthalpy and H decreases) or (TΔS increases) or both
Verbally explain -ΔG
Spontaneous processes decreases the system’s free energy
+ ΔG
Nonspontaneous
Verbally explain +ΔG
Nonspontaneous reactions increases the system’s free energy
Free energy is like a
measure of a system’s instability
Unstable systems (higher G) tends to change to become
more stable (lower G)
Name three examples of how unstable systems become more stable
Gravitational motion (Diver goes from higher to lower altitude)
Diffusion (Molecules of dye disperse)
Chemical Reaction (Glucose is broken down into simpler molecules)
Exergonic Reaction
net release of free energy (-ΔG)
Endergonic Reaction
Absorbs free energy from its surroundings (+ΔG)
Why is metabolism fundamental to life’s…uh…lifeness
It is never at equilibrium!
Energy Coupling
Use of exergonic processes to drive an endergonic one
ATP + H2O ->
How much G is released?
ADP + Pi
ΔG = -7.3 kcal/mol per mol of ATP
Enzyme
A macromolecule (usually proteins here) that acts as a catalyst
Catalyst
A chemical agent that speeds up a reaction without being consumed by the reaction
Activation Energy (E sub A)
The initial investment of energy to start a reaction
Enzymes cannot
change the ΔG of a reaction (make a endergonic reaction exergonic)