ORGANiC MOLECULES(carbohydrates) Flashcards

1
Q

why are carbohydrates the most abundant organic molecules

A

because of the abundance of photosynthetic organisms like plants and algae

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2
Q

essential proteins

A

proteins that cannot be coded for by our DNA and should therefore be consumed in our diet

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3
Q

what is the essence of flavin nucleotides?

A

they are important for oxidation-reduction reactions

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4
Q

when in a protein structure, amino acids are referred to as

A

residues

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5
Q

what are blood group distinctions between certain people due to

A

specific sugars on the red blood cells

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6
Q

how are carbohydrates classified?

A

based on the;
number of sugars present
number of carbon atoms
the functional group

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7
Q

carbohydrates with between 3-10 sugars present

carbohydrates with more than 10 sugars present

A

Oligosaccharides

polysaccharides

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8
Q

how are monosaccharides numbered?

A

numbered beginning at the end that contains the carbonyl carbon

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9
Q

The general formula of carbohydrates

A

(CH20)n
n represents the number of carbon atoms

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10
Q

aldoses

ketoses

A

carbohydrates with the carbonyl group at the end of the molecule

carbohydrates with the carbonyl group elsewhere in the molecule

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11
Q

isomers

A

compounds with the same chemical(molecular) formula but different structures

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12
Q

constitutional isomers

A

they differ in the order of attachment of atoms

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13
Q

diastereoisomers

the two classifications of diastereoisomers

A

isomers that are not mirror images of each other

epimers and anomers

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14
Q

epimers

anomers

A

carbohydrate isomers that only differ in configuration around one specific carbon
atom(with the exception of the carbonyl carbon atom)

isomers that differ on a new asymmetric carbon formed on ring closure

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15
Q

pyran

A

a six-membered ring

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16
Q

difference between alpha and beta glucose

A

the hydroxyl group is below the carbon 1 atom in an alpha glucose molecule and above it in a beta glucose molecule

17
Q

when is acyclic monosaccharide considered
alpha
beta

A

when the CH2OH(containing carbon 6) group is opposite the hydroxyl group

when the CH2OH(containing carbon 6) group is on the same side as the hydroxyl group

18
Q

furan

A

a five-membered ring

19
Q

anomeric carbon

A

after cyclization, the former carbonyl carbon is referred to as the anomeric carbon

20
Q

for a monosaccharide enantiomer to be considered as D or L, which carbon should be considered

when is the enantiomer considered a D
when is the enantiomer considered a L

A

carbon 5

when the OH group is on the right of carbon 5
when the OH group is on the left of carbon 5

21
Q

the bond that links monosaccharides is known as?
which enzymes catalyze the formation of this bond?

A

Glycosidic bond

glycosyltransferases

22
Q

what are the monosaccharides that make up the following up the following;
lactose

maltose

sucrose

A

beta galactose and alpha glucose

alpha glucose and alpha glucose

alpha glucose and beta fructose

23
Q

are all monosaccharides reducing sugars? why?

A

yes
because the hydroxyl group on the anomeric carbon is not linked to any other molecule, so it can be an open ring

24
Q

the storage form of glucose in animals

A

glycogen

25
Q

GLYCOGEN
subunits
bonds
branches ?

A

alpha glucose
1-4 and 1-6 glycosidic bonds
yes, there is a branch after every ten subunits

26
Q

CELLULOSE
subunits
bonds
branches?

A

beta glucose
1-4 glycosidic bonds
no

27
Q

STARCH FORMS?
AMYLOSE
subunits
bonds
branches?

AMYLOPECTIN
subunits
bonds
branches?

A

two, amylopectin and amylose

alpha glucose
1-4 glycosidic bonds
no

alpha glucose
1-4 and 1-6 glycosidic bonds
yes, there are branches after every 20 subunits

28
Q

which between amylopectin and glycogen is able to store more energy and why

A

glycogen, as it is more compact due to there being more branches

29
Q

If the hydroxyl group on the anomeric carbon in a cyclic monosaccharide is not linked to another compound, then what happens?

A

the ring can open, and the sugar can therefore act as a reducing agent, thereby the name reducing sugars.

30
Q

in complex carbohydrates, If the group on the non-carbohydrate molecule to which the sugar is attached is an –NH2 group, then what name is given to;
the structure formed
the bond formed

If the group on the non-carbohydrate molecule to which the sugar is attached is an OH group, the what name is given to;
the structure
the bond formed

A

N-glycoside

N- glycosidic link

O-glycoside
O-glycosidic link

31
Q
A