IFSTA CH 4 Fire Dynamics Flashcards
physical change
substance remains chemically the same but changes in size, shape or appearance (ex. freezing/boiling)
Chemical reaction
occurs when a substance changes from on type of matter into another
oxidation
chemical reaction involving the combination of an oxidizer with other materials
timeline of oxidation
potential energy
the amount of energy that an object can release at some point in the future
kinetic energy
energy that a moving object possesses
exothermic reaction
reactions that emit energy as they occur
ex. Fire, releases energy in the form of heat and sometimes light
endothermic reaction
reactions that absorb energy as they occur
ex. converting water to steam
fire triangle
Fire Tetrahedron
eliminate any of the elements in the fire triangle
the fire will be extinguished
ignition
fuels must be in a gaseous state in order to burn
pyrolysis
occurs when a solid fuel is converted into a gaseous fuel
vaporization
is the conversion of a liquid to a vapour by heat energy
piloted ignition
most common form of ignition
occurs when a mixture of fuel and oxygen encounter an external heat source with sufficient heat or thermal energy to start the combustion reaction
autoignition
occurs without any external flame or spark to ignite the fuel gases or vapours
autoignition temperature (AIT)
minimum temp at which a fuel in the air must be heated in order to start self-sustained combustion
always higher then its piloted ignition temperature
two modes of combustion
flaming and non-flaming
non-flaming combustion
occurs more slowly and at a lower temperature, producing a smoldering glow in the materials surface (fire triangle)
flaming combustion
commonly referred to as fire
produces a visible flame above the materials surface
occurs when a gaseous fuel mixes with oxygen in the correct ratio and heats to ignition temperature (fire tetrahedron)
products of combustion
often described as heat and smoke
materials produced and released during burning
incomplete combustion
smoke is a product of incomplete combustion
combustion is incomplete when any of the fuel is left after combustion has occurred
has the potential to burn
carbon monoxide
toxic and flammable product of the incomplete combustion of organic materials
colorless and odorless gas
acts as a chemical asphyxiant (frequent cause of death in civilians)
hydrogen Cyanide (HCN)
toxic flammable substance produced int he combustion of materials containing nitrogen
is a significant byproduct of the combustion of polyurethane foam used in many household furnishing
is 35x more toxic than CO
HCN prevents the body from using oxygen at the cellular level
carbon dioxide
is a product of complete combustion of organic materials
it displaces existing oxygen which creates an oxygen deficient atmosphere
pressure
is the force per unit of area applied perpendicular to a surface
gases always move from areas of higher pressure to areas of lower pressure
health effects of CO
health effects of HCN
Heat
is the thermal kinetic energy needed to release the potential chemical energy in a fuel
temperature
is the measure of heat
heat (HRR) - candle example
one candle burns at the same temperature as ten candles
however the heat release rate of the ten candles is 10x greater than on candle at the same temperature
HRR and PPE
the temperature tells you it is safe to go in but the heat transfer rate - not the temperature - tells you how long you can stay in
chemical energy
most common source of heat in combustion reactions
self-heating
a form of oxidation
is a chemical reaction that increases the temperature of a material without the addition of external heat
spontaneous ignition
ignition without the addition of external heat
electrical energy can occur in several ways, including
resistance heating
overcurrent or overload
arcing
sparking
resistance heating - electrical
electric current flowing through a conductor produces heat
overcurrent or overload - electrical
when the current flowing through a conductor exceeds its designed limits
arcing
high-temp electric discharge across a gap or through a medium
sparking - electrical
when an electric arc occurs, glowing particles can form and splatter away from the arcing point
temperature - Celsius/Fahrenheit conversion
mechanical energy
friction and compression generate mechanical energy
movement of two surfaces against each other
compressed gas