Bonds Flashcards
Bond dissociation energy
Energy needed to break a bond homolytically
Homolytic bond cleavage
One electron of cleavage goes to each fragment of molecule and two radicals are formed
Heterolytic bond cleavage
Both electrons making up bond end up on same atom
What type of bond has higher dissociation energy?
Triple bond
If a molecule has a high percentage of p character is the bond strong or weak?
Weak and bond is longer
If a molecule is sp3 what is the bond angle and orbital geometry?
109.5 and tetrahedral
If molecule is sp2 what is bond angle and orbital geometry?
120 and trigonal planar
If molecule is sp what is bond angle and orbital geometry?
180 and linear
If there is one electron pair what is shape and orbital geometry?
Trigonal planar and bent
If there is one lone pair and molecule is tetrahedral what is its shape?
Trigonal pyramid
If there is two lone pairs and molecule is tetrahedral what is the shape?
Bent
Sigma bonds
Two electrons localized between two nuclei
Pi bonds
Double bonds
Vapor pressure
Pressure exerted by gas phase of liquid that evaporated from exposed surface of liquid.
If intermolecular forces are weak, what is vapor pressure?
High