AAMC FL3 C/P Flashcards

1
Q

Doppler equation

A
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2
Q

if someone is moving towards a stationary sound source, how doe the perceived frequency change

A

frequency is increases because (v + vo) / v > 1

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3
Q

if someone is moving away from a stationary sound source, how does the perceived frequency change

A

frequency decreases because (v - vo) / v < 1

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4
Q

if a sound source is moving towards a stationary person, how does the perceived frequency change

A

frequency increases because v / (v - vs) > 1

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5
Q

if a sound source is moving away from a stationary person, how does the perceived frequency change

A

frequency decreases because v / (v + vs) < 1

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6
Q

1 joule =

A

1 newton x meter

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7
Q

1 watt =

A

1 joule / second

(work / time)

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8
Q

uniform electric field

A

a field in which the value of the field strength remains the same at all points

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9
Q

resistance and conductivity relationship

A

they are inversely related!

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10
Q

resistance units

A

ohm’s

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11
Q

period vs frequency

A

period → seconds per cycle

frequency → cycles / second

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12
Q

newton units

A
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13
Q

transferase

A

enzymes that catalyse the transfer of specific functional groups (e.g. a methyl or glycosyl group) from one molecule to another (donor to acceptor)

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14
Q

nucleotide vs nucleoside

A

Nucleosides → nitrogenous base + a five-carbon carbohydrate group (usually ribose)

Nucleotides → a nucleoside with one or more phosphate groups attached

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15
Q

what is this structure called

A

heme group

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16
Q

michaelis menton plot

A

x-axis → substrate concentration

y-axis → INITIAL reaction rate (before the reverse reaction occurs)

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17
Q

why do we use smaller enzyme concentrations than substrate concentrations to measure enzyme kinetics?

A

enzyme kinetics involves seeing how the substrate concentration affects the initial reaction rate

if we have more enzyme than substrate, each trial would be the same

18
Q

what is a heme?

A

a porphyrin ring with iron in the center

19
Q

hydroxylation

A

that addition of a hydroxyl group onto a compound

20
Q

hydrolase

A

enzymes that catalyze hydrolysis (cleave bonds by adding water)

21
Q

ligase

A

enzyme that catalyzes bond formation between 2 (larger) molecules

22
Q

transferase enzyme

A

catalyze the transfer of a functional group (amine, carboxyl, carbonyl, methyl, acyl, etc.) from one molecule to another

23
Q

lyase enzyme

A

catalyzes the breaking of various chemical bonds by means other than hydrolysis and oxidation

24
Q

standard Gibb’s free energy (derived from Keq)

A
25
Q

Standard free energy of a reaction

A

the free energy change that occurs when the ruction is carried out under standard state conditions

26
Q

if current pH is BELOW the pKa ….

A

the proton is attached to the molecule still

27
Q

if current pH is ABOVE the pKa ….

A

the proton has been released from the molecule into solution

28
Q

as pH rises, molecules are being more readily _______ (protonated/deprotonated)

A

deprotonated

they lose their H+ ions to solution to interact with the available base

29
Q

isoelectric point

A

the pH of a solution at which the net charge of a protein becomes zero

if pH < IP; protein is positively charged

if pH > IP; protein is negatively charged

30
Q

FORMAL CHARGE

A

(# valence electrons in neutral/lone atom) – (# bonds + nonbonding electrons)

31
Q

valence electrons in nitrogen

A

5

32
Q

valence electrons in oxygen

A

6

33
Q

valence electrons in carbon

A

4

34
Q

what is Kw?

A

dissociation constant or ionization constant of water

1 x 10^-14 at 298K

35
Q

stronger acid = ______ ka

A

larger

dissociates more readily

36
Q

if ka > kb, the solution is _____ (acidic/basic)

A

acidic

37
Q

if kb > ka, the solution is _____ (acidic/basic)

A

basic

38
Q

aufbau principle

A

electrons fill lower-energy atomic orbitals before filling higher-energy ones

39
Q

chelate

A

a compound containing a ligand (typically organic) bonded to a central metal atom at two or more points

40
Q

celcius to Kelvin

A

K = C + 273