Polyamides Flashcards
Examples of condensation polymerisation
Polyesters
Polyamides
Polypeptides
Polyamides is made from
DiCarboxylic acids + diamines (2 NH2 groups)
Polypeptide is made from
Amino acids
How to draw the repeat unit of a condensation polymer
Find the amide/peptide/ ester link
Take a H and OH off each molecule
Draw square brackets around
Have bonds from each end that extend out of the square brackets
Polyamides link name
Amide link
Polypeptide link name
Peptide bond
What does condensation of diamine + carboxylic acid release?
H2O molecules
Acid Hydrolysis of polyamide
Releases dicarboxylic acid
And dialkylammonium ion(NH3+ on both ends)
Alkali hydrolysis of polyamide
Releases diarboxylate ion
And diamine
Why are polyamides biodegradable?
Can be hydrolysed by breaking amide link to release monomers
Intermolecular forces between polyamides
Hydrogen bonds
Permanent dipole-dipole interactions
London forces