Kc constant Flashcards
What is Kc?
The equilibrium constant
Gives us an idea of how far left or to the right the position of equilibrium is
What 2 methods are used to calculate the Kc?
Heterogeneous equilibrium
Homogeneous equilibrium
Homogeneous equilibrium
Calculating the Kc when all reactants and products are in the same state
What values are used in homogeneous equilibrium?
ALL
Kc expression
[Conc of product]
————————
[conc of reactant]
May be multiple
To the power of the stoichoometry
Heterogeneous equilibrium
Calculating the Kc when not everything is in the same physical state
What values are used in heterogeneous equilibrium?
DONT INCLUDE PURE LIQUIDS (l)
DONT INCLUDE SOLIDS (s)
Why not use liquids or solids in equilibrium constant?
Because their concentrations stay constant throughout the reaction
What factors affect the equilibrium constant?
None of them except temperature
What happens if equilibrium constant has increased?
The position of equilibrium shifts to favour the forward reaction
What happens if equilibrium constant decreases?
The position of equilibrium shifts to favour the backwards reaction
Why does the position of equilibrium shifting right due to changes in temperature mean the Kc value increases?
Because then the concentration of products has increased and the concentration of reactants has decreased
So the equilibrium constant fraction gets larger on top than bottom (increased value)
If increasing the temperature causes the Kc to decrease, what does this tell us?
This means the position of equilibrium has shifted to the left because the Kc has decreased (fraction smaller on top than bottom in constant)
So therefore the backwards reaction is endothermic (shifted this way when temp increases)
And forwards reaction is exothermic
Why does changing concentration not effect Kc value?
Because the position of equilibrium shifts in order to oppose the increase of one reactants’s conc
So this will reach a balance in order to revert the Kc value back to how it originally was by increasing the conc of reactants on other side