Iodine thiosulfate titration Flashcards
Thiosulfate ions formula
S₂O₃²⁻
Equation
S₂O₃²⁻ + I₂ —-> S₄O₆²⁻ + 2I⁻
idea for this titration
Find out the concentration of iodine in a sample by titrating against a standard solution of thiosulfate ions (S₂O₃²⁻)
Indicator used to clarify end point
Starch
End point of this reaction
All the iodine in conical flask has reacted with thiosulfate and reduced to I-
So when starch indicator is added, no blue black colour remains
Colour change for end point
Straw colour in conical flask (iodine) decolourises to colourless
Why can starch indicator clarify end point?
A drop to conical flask turns blue black to show iodine is still present so continue the titration
When is the starch indicator added?
When the light brown becomes more pale to show little iodine is remaining:most has been reduced to iodide
So we clarify end point with starch