Lecture 2 Flashcards

1
Q

No net gain or loss of energy is classified as what

A

dynamic dteady state

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2
Q

exchange both energy and matter with its surroundings is defined as what

A

open systeem

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3
Q

total amount of energy in the universe stays constant, which law

A

first law of thermodynamics

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4
Q

entropy (randomness) is always increasing in the universe, which law

A

second law of thermodynamics

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5
Q

what is delta g when rxn is exergonic

A

negative

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6
Q

what is delta g when rxn is endergonic

A

positive

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7
Q

in closed systems, rxns proceed spontaneously until what

A

equilibrium is reached

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8
Q

electrostatic attraction btw 1 e/n atom and a hydrogen atom covalently linked to a second en atom

A

hydrogen bond

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9
Q

what are atoms that can make hydrogen bonds

A

H, N, O, F

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10
Q

are hydrogen bonds weak or strong

A

weak

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11
Q

which region interacts favorably with water

A

polar, hydrophilic region

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12
Q

lipids in water causes what

A

lipids become highly ordered

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13
Q

what’s crucial to macromolecular structure and function

A

weak interactions

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14
Q

measure of solute in a solvent

A

osmolarity

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15
Q

water moves in, cell swells

A

cell in hypotonic soln

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16
Q

water moves out and cell shrinks

A

cell in hypertonic soln

17
Q

what are the colligative properties of solvent

A

bp, vp, mp, osmotic pressure

18
Q

how to find pH

A

-log [H+]

19
Q

how to find pKa

A

-log [Ka]

20
Q

aqueous systems that tend to resist changes in pH when small acid or base are added

A

buffer

21
Q

what does a buffer system consist of

A

weak acid and its conjugate base

22
Q

how is overall buffer conc determined

A

add the conc of wa and conj base

23
Q

at midpoint, the ph of solution equals what

A

pKa

24
Q

buffering region is what

A

+ or - 1 of pKa

25
Q
A