Carbs Flashcards

1
Q

Name four biomolecules (C,H,O,N)

A

1.Carbs
2.Proteins
3.Lipids
4.Nuclei Acids

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2
Q

Empirical formula for hydrates of Carbon

A

CH2O

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3
Q

What is the most abundant organic molecule in nature?

A

Carbs

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4
Q

4 Functions of Carbs?

A

1.Dietary requirement
2.Energy Storage
3.Component of Cell membranes (Glycolipids etc)
4.Structural component of many organisms(cellulose)

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5
Q

Name two monosaccharides

A

1.Glucose

2.Fructose

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6
Q

Name two disaccharides

A

1.Maltose (2 Glucose)
2.Lactose (galactose and glucose)
3.Sucrose (Fructose and glucose)

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7
Q

Name three oligosaccharides

A

1.Raffinose
2.maltotriose
3.Oligofructose

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8
Q

Name three polysaccharides

A

Starch (linear)
Cellulose
Glycogen(Branches)

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9
Q

What reaction can monosaccharides not undergo?

A

They cannot be hydrolysed (hydrolysis)

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10
Q

Can be same structural isomer but different name, why?

A

Different functional groups

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11
Q

What is the difference between Aldose and ketone?

A

If the C=O (carbonyl carbon) is at the end it is an Aldose
If it’s elsewhere it is a ketone

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12
Q

What is an isomer?

A

Compounds with the same chemical formula but different structure (e.g) glucose,Fructose.

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13
Q

What is an Epimer?

A

Where one carbon along the chain is different

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14
Q

What is an enantiomer?

A

A molecule is a mirror image of another (non-superimposable)

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15
Q

Are most human sugars D-arranged or L-Arranged?

A

Most sugars in humans are D-

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16
Q

What sides are D- and L- assigned?

A

D- = Left
L- = Right

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17
Q

What percentage of monosaccharides exist as open chained?

A

1% and the rest are a ring formation

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18
Q

What type of carbon is formed when cyclisation occurs within a monosaccharide?

A

An anomeric carbon is created

19
Q

What side is the -OH group on an Alpha glucose

A

Alpha=downwards (fish)

20
Q

What side is -OH on a Beta Glucose?

A

OH = upwards (bird)

21
Q

What can monosaccharides form when they bond together (-saccharides)?

A

They can create di-,oligo-, or polysaccharides

22
Q

What reaction and bonds occur when monosaccharides bond together?

A

A condensation reaction occurs and creates glycosidic bonds

23
Q

What catalyses creation of glycosidic bonds?

A

Glycosyltransferase

24
Q

Name three important polysaccharides that are all polymers of glucose

A

Glycogen, Starch, Cellulose

25
How is an alpha bond characterised?
If the anomeric hydroxyl is in Alpha configuration
26
How is a beta bond characterised?
If the anomeric hydroxyl group is in beta configuration
27
What is possible if the anomeric hydroxyl group is not bonded to another compound?
It is possible for the ring to open and for the sugar to act as a reducing agent
28
Are all monosaccharides reducing sugars?
Yes all monosaccharides are reducing sugars
29
What can reducing sugars react with and what do they do to the reagent?
They can react with chromatic agents (e.g detect sugars in urine) and cause the reagent to become reduced and coloured
30
What group do reducing sugars oxidise?
They oxidise the aldehyde group of the cyclic sugar (E.g Benedict’s test)
31
What’s are the biomedical importances of Glucose?
1.main sugar and important energy source in all cells. 2.Ribose in nucleotides and nucleic acids. 3.Forms glycoproteins, glycolipids, and lipids.
32
Why is glucose stored as polymers and what polymer?
They are stored as glycogen(cosmetically inactive) as it is compact and also large surface area, also if stored as glucose it affects osmotic balance
33
Where is glycogen mainly found?
Glycogen is found mainly in the Liver and muscle cells.
34
What bonds are present in Glycogen?
Alpha 1,6 and 1,4 bonds.
35
How often do Alpha 1,4 bonds in glycogen occur?
Once every 10 units of glucose causing branching (via branching/debranching enzymes)
36
What is starch composed of and its function in a plant?
It is a storage of glucose, and composed of two polysaccharides
37
What are the two polysaccharides in starch?
Amylose and amylopectin
38
Structure of amylose?
1,4 bonds only making it linear, 1 reducing and non reducing end
39
Structure of amylopectin?
Alpha 1,4 and 1,6 bonds causing branching, many non reducing ends but one reducing end
40
How often does amylopectin branch?
Once every 20-30 units of glucose
41
What is the function of cellulose and is it abundant?
A structural polysaccharide in plant cell walls which is the most abundant organic molecule on earth.
42
What is cellulose also known as and why is it indigestible to mammals?
AKA fibre and is indigestible because mammals lack cellulase
43
What type of bonds are in Cellulose?
Chains of Beta 1,4 glycosidic bonds.