5.1.3- Acids, Bases and Buffers Flashcards
Define Brønsted-Lowry base
Proton (H+ acceptor)
Define Brønsted-Lowry acid
proton (H+) donor
Acid plus metal goes to…
Salt plus hydrogen
Acid plus carbonate goes to…
Salt plus water plus carbon dioxide
Acid plus base goes to…
Salt plus water
Acid plus alkali goes to…
Salt plus water
Define a neutralisation reaction
A chemical reaction in which an acid and a base react together to produce a salt and water
Define a conjugate acid-base pair
Two species that transform into each other by gain or loss of a proton
Define a conjugate acid
A species formed when a proton is added to a base
Define a conjugate base
A species formed when a proton is taken from an acid
What is the formula of the hydronium ion
H3O+
Define a strong acid
An acid that completely dissociates in solution
Define a week acid
And acid that partially dissociates in solution
What is the acid dissociation constant
It shows you the extent of acid dissociation
Ka=[H+][A-]/[HA]
Define pH
pH= -log[H+]
What does [H+] mean and equal
The concentration of H plus ions
[H+]=10^-pH
What is the Ionic product of water (Kw)
Kw = [H+][OH-] = 1.00 x 10-14 mol2dm-6 at 298K
Define a buffer solution
A system that minimises pH changes in addition of small amounts of acid or base
What makes a buffer solution
A weak acid and its conjugate base. For example you can mix a weak acid with a salt of the weak acid eg. CH3COOH/CH3COONa
How does a buffer solution reduce pH changes on the addition of acid (H+)
- [H+] is increased
- The conjugate base A- reacts with the H+
- The equilibrium shifts left removing most of the added H+
How does a buffer solution reduce pH changes on the addition of base (OH-)
- [OH-] is increased
- The H+ ions react with the OH-
- The weak acid HA dissociates to replace most of the H+ that reacted.
Name the buffer solution that controls blood pH
Carbonic acid - hydrogencarbonate buffer solution (H2CO3 - HCO3-)
What pH range should blood be kept to
7.35-7.45
Define the equivalence point
The point in a titration at which the volume of one solution has reacted entirely with the volume of the second solution
Define the end point
The endpoint of an indicator is the point in the titration at which there are equal concentrations of the week acid and conjugate base forms of the indicator.
Define the standard enthalpy change of neutralisation
The Energy change that accompanies the neutralisation of an aqueous acid by an aqueous base to form one mole of H2O under standard conditions