5.1.3- Acids, Bases and Buffers Flashcards

0
Q

Define Brønsted-Lowry base

A

Proton (H+ acceptor)

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1
Q

Define Brønsted-Lowry acid

A

proton (H+) donor

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2
Q

Acid plus metal goes to…

A

Salt plus hydrogen

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3
Q

Acid plus carbonate goes to…

A

Salt plus water plus carbon dioxide

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4
Q

Acid plus base goes to…

A

Salt plus water

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5
Q

Acid plus alkali goes to…

A

Salt plus water

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6
Q

Define a neutralisation reaction

A

A chemical reaction in which an acid and a base react together to produce a salt and water

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7
Q

Define a conjugate acid-base pair

A

Two species that transform into each other by gain or loss of a proton

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8
Q

Define a conjugate acid

A

A species formed when a proton is added to a base

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9
Q

Define a conjugate base

A

A species formed when a proton is taken from an acid

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10
Q

What is the formula of the hydronium ion

A

H3O+

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11
Q

Define a strong acid

A

An acid that completely dissociates in solution

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12
Q

Define a week acid

A

And acid that partially dissociates in solution

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13
Q

What is the acid dissociation constant

A

It shows you the extent of acid dissociation

Ka=[H+][A-]/[HA]

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14
Q

Define pH

A

pH= -log[H+]

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15
Q

What does [H+] mean and equal

A

The concentration of H plus ions

[H+]=10^-pH

16
Q

What is the Ionic product of water (Kw)

A

Kw = [H+][OH-] = 1.00 x 10-14 mol2dm-6 at 298K

17
Q

Define a buffer solution

A

A system that minimises pH changes in addition of small amounts of acid or base

18
Q

What makes a buffer solution

A

A weak acid and its conjugate base. For example you can mix a weak acid with a salt of the weak acid eg. CH3COOH/CH3COONa

19
Q

How does a buffer solution reduce pH changes on the addition of acid (H+)

A
  1. [H+] is increased
  2. The conjugate base A- reacts with the H+
  3. The equilibrium shifts left removing most of the added H+
20
Q

How does a buffer solution reduce pH changes on the addition of base (OH-)

A
  1. [OH-] is increased
  2. The H+ ions react with the OH-
  3. The weak acid HA dissociates to replace most of the H+ that reacted.
21
Q

Name the buffer solution that controls blood pH

A

Carbonic acid - hydrogencarbonate buffer solution (H2CO3 - HCO3-)

22
Q

What pH range should blood be kept to

23
Q

Define the equivalence point

A

The point in a titration at which the volume of one solution has reacted entirely with the volume of the second solution

24
Define the end point
The endpoint of an indicator is the point in the titration at which there are equal concentrations of the week acid and conjugate base forms of the indicator.
25
Define the standard enthalpy change of neutralisation
The Energy change that accompanies the neutralisation of an aqueous acid by an aqueous base to form one mole of H2O under standard conditions