2.2 WATER Flashcards
Hydrogen bonding
Water Ms are polar+ H bonds form between them
- Water M attraction= ‘H bond’
- Intermolecular force/not bond
• Force: H atom in 1 polar M is attracted to a slightly –ve atom of another polar covalent M
cohesive
- Binding together 2 M of same type
- Water M cohere: stick to each other
- →Due to H bond
- Useful for water transport in plants
- Water suck through xylem at low P
- →Only if water M don’t separate
adhesive
- H bonds form between water and other polar M= water sticks to them
- Useful in leaves: water adheres to cellulose M in cell walls
- If water evaporates from cell walls and is lost from the leaf via the network of air spaces, adhesive forces cause water to be drawn out of the nearest xylem
- Keeps walls moist: so that they can absorb CO2 needed for photosynthesis
PROPERTIES OF WATER
Hydrogen bonding + dipolarity explain water’s cohesive, adhesive, thermal and solvent properties
solvent
- Polar nature of water M forms shells around charged/polar M prevents clumping/keep in solution
- Water forms H bonds with polar M
- Partial –ve O2 pole→+ve ions
- Partial +ve H pole→-ve ions: both dissolve
- Cytoplasm is a complex mixture of dissolved subs
WATER THERMAL
high specific heat capacity
High specific heat capacity • H bonds restrict motion of water M + increases in the T of water require H bonds to be broken • Q of E needed to raise water T: > • To cool down: water loses > E • Water T is stable: good habitat
HYDROPHILIC/ HYDROPHOBIC
Subs can be hydrophilic/phobic
- Philic: attracted to water
- All subs that dissolve in H2O
- Polar M + particles: +/-ve
- Subs that water adhere to
- Phobic: insoluble in water yet dissolve in other solvent
- M with no -/+ ve charge
- Non polar M
- All lipids: fats + oils
COOLING THE BODY WITH SWEAT
- Heat needed for evaporation of water in sweat is taken from tissue of skin: reducing their T
- Effective method as body has high latent heat of v.
- Hypothalamus (brain) controls sweat secretion
- Receptors monitor blood T/ sensory inputs
- Transpiration is evaporation loss of water from plant leaves: cooling effect for hot environments
TRANSPORT IN BLOOD PLASMA overview
Methods of transport of subs in blood relative to their H20 solubility
TRANSPORT IN BLOOD PLASMA
AMINO ACID
Amino Acid: both -/+ve charges→
soluble in water but solubility depends on the R group: some hydrophilic/phobic.
All A.A are soluble enough to be carried in blood plasma
TRANSPORT IN BLOOD PLASMA
GLUCOSE
Glucose: freely soluble polar M carried dissolved in blood p.
TRANSPORT IN BLOOD PLASMA
OXYGEN
O2: non-polar M w/ < size dissolves only sparingly in water
water becomes saturated with O2 at low conc.
Q (O2) that blood p carries is < to provide aerobic R→
sol: haemoglobin in RBC has binding sites for O2
+ > blood capacity of O2 transport
TRANSPORT IN BLOOD PLASMA
FAT
Fat M: entirely non-polar, >02, insoluble in water. They are carried in blood inside lipoprotein complexes.
TRANSPORT IN BLOOD PLASMA
CHOLESTEROL
Cholesterol: Hphobic M, apart form small philic region at 1 end. Not enough to dissolve so carried in lipoprotein complexes.
comparing methane and water
Property Methane Water
Formula CH4 H20
Molecular Mass 16 18
Density g/cm3 0.46 1
Specific heat capacity J/g/*C 2.2 4.2
Latent vaporization heat J/g 760 2,257
Melting point *C -182 0
Boiling Point -160 100