MIDTERM 23 - Tannins Flashcards
Are mixtures of polyhydroxy phenolic compounds which are difficult to separate because they do not crystallize
Tannins
Are commonly used as astringent, antidote to alkaloidal poisoning, tanning, and dyeing industry
Tannins
Hamamelis (Scientific name)
Hamamelis virginiana
Hamamelis (Family)
Hamamelidaceae
Hamamelis (Constituent)
Hamamelitannin
Used as an astringent and for its hemostatic effect (Tannin plants)
Hamamelis
Nutgalls (Scientific name)
Quercus infectoria
Nutgalls (Family)
Fabaceae
Nutgalls (Common name)
Turkish Syrian or Aleppo galls
Nutgalls (Constituent)
Gallotannin
Goldbeater’s skin test/Skin tanning test (2 composition)
25% HCl, 15% solution of ferrous SO4
Goldbeater’s skin test/Skin tanning test (Positive result)
Brown/black color
Gelatin test (Composition)
10% gelatin solution
Gelatin test (Positive result)
White ppt
Test with phenazone (2 composition)
0.5 g sodium acid phosphate, 2% phenazone solution
Test with phenazone (Positive result)
All tannins are precipitated (Bulky and often colored)
Test with ferric chloride (Composition)
5% ferric chloride
Test with ferric chloride (Positive result)
Bluish-black color (Hydrolyzable tannins), Greenish brown (Non-hydrolyzable tannins)
Test with bromine water (Composition)
Bromine water solution
Test with bromine water (2 positive results)
Do not form any ppt (Hydrolyzable tannins), Buff colored ppt (Non-hydrolyzable tannins)
Test for chlorogenic acid (Composition)
Ammonia
Test for chlorogenic acid (Positive result)
Green color
Test with lead nitrate (Composition)
5% lead nitrate
Test with lead nitrate (Positive result)
White ppt
Test with iodine (Composition)
Iodine solution
Test with iodine (Positive result)
Red color
Test with nitric acid (Composition)
Nitric acid
Test with nitric acid (Positive result)
Red to yellowish color