MIDTERM 11 - Alkaloids Flashcards

1
Q

Derived from amino acid and share a heterocyclic ring with nitrogen (Types of alkaloids)

A

True alkaloids

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2
Q

Compounds which the N atom is derived from amino acids and not part of heterocyclic ring (Types of alkaloids)

A

Proto/amino alkaloids

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3
Q

Cocaine, quinine, and morphine are examples of __________

A

True alkaloids

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4
Q

Hordenine, mescaline, and yohimbine are examples of ___________

A

Proto/amino alkaloids

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5
Q

The basic carbon skeletons of which are not derived from amino acid (Types of alkaloids)

A

Pseudo alkaloids

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6
Q

Are non alkaloids that give a false positive reaction with alkaloidal reagents (Types of alkaloids)

A

False alkaloids

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7
Q

Coniine, capsaicin, ephedrine, caffeine, and theobromine are examples of __________

A

Pseudo alkaloids

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8
Q

Most alkaloids are __________, only a few alkaloids are amorphous (like emetine)

A

Crystalline solid

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9
Q

Majority of alkaloids are __________

A

Colorless

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10
Q

Colchicine and berberine are color __________

A

Yellow

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11
Q

Canadine is color __________

A

Orange

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12
Q

Salts of sanguinarine are color _________

A

Copper red

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13
Q

Alkaloidal bases and salts are soluble in __________

A

Alcohol

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14
Q

Most of the alkaloids ends in __________

A

“-ien”

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15
Q

All alkaloids are solids, except __________, __________, __________, and __________ (CANS)

A

Coniine, Arecoline, Nicotine, Sparteine

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16
Q

Derived from Coniium maculatum (poison hemlock)

A

Coniine

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17
Q

Cocaine (Stimulant, hallucinogen, or depressant)

18
Q

Ephedrine (Stimulant, hallucinogen, or depressant)

19
Q

Caffeine (Stimulant, hallucinogen, or depressant)

20
Q

Tropane alkaloids (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

21
Q

Mescaline (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

22
Q

Ergot alkaloids (Stimulant, hallucinogen, or depressant)

A

Hallucinogen

23
Q

Morphine (Stimulant, hallucinogen, or depressant)

A

Depressant

24
Q

Codeine (Stimulant, hallucinogen, or depressant)

A

Depressant

25
Q

Heroin (Stimulant, hallucinogen, or depressant)

A

Depressant

26
Q

Nicotinic precursor

27
Q

Purine precursor

28
Q

Some alkaloids are synthesized from __________ along mevalonic acid pathway

29
Q

Atropine is an example of __________

A

True alkaloid

30
Q

Ephedrine is an example of __________

A

Protoalkaloid

31
Q

Caffeine is an example of __________

A

Pseudo alkaloid

32
Q

Reddish-brown/Brown ppt (Chemical test for alkaloids)

A

Wagner’s test

33
Q

Wagner’s test (Positive result)

A

Reddish-brown/Brown ppt

34
Q

White/Cream color ppt with true alkaloids (Chemical test for alkaloids)

A

Mayer’s test

35
Q

Mayer’s test (Positive result)

A

White/Cream color ppt with true alkaloids

36
Q

Yellow ppt with true alkaloids (Chemical test for alkaloids)

A

Hagger’s test

37
Q

Hagger’s test (Positive result)

A

Yellow ppt with true alkaloids

38
Q

Reddish brown ppt/Orange yellow ppt/ Orange ppt (Chemical test for alkaloids)

A

Dragendorff’s test

39
Q

Dragendorff’s test (Positive result)

A

Reddish brown ppt/Orange yellow ppt/ Orange ppt

40
Q

Are alkaloids that arise by inclusion of a basic nitrogen at some point in the steroid molecule; C27 compounds having cyclopentanophenanthrene moiety

A

Steroidal alkaloids