DM - fibre reinforced composites (FRC) Flashcards
what is fibre reinforced composite composed of?
synthetic material (polymer and fibres)
fibres - glass
the fibres support the composite
what types of glass fibres are used in the dental industry?
E-glasses
R-glasses
S-glasses
how is E-glass modified to make it more resistant to acid attacks?
Addeding Boron Oxide and reducing CaO
addition of what can compromise the strength of fibres?
fillers
what types of polymers can be in FRC?
linear (MMA/PMMA)
cross-linked (EDGMA, bis-GMA, epoxi resins)
semi interpenetrating polymer network (comb of both)
difference between linear polymers and cross-linked polymers?
linear - thermoplastic
cross-linked - thermoset
what type of polymer is ideal for FRC and why?
semi-IPN
better clinical handling property
better bonding to indirect restorations
higher toughness
what is resin impregnaton?
surface wetting properties of fibres by the resin, distance of the individual fibres from each other and viscosity of resin material
describe the reimpregnation method
PMMA is dissolves in a high evaporative solvent
the solvent evaporates and the fibres stay impregnated with PMMA
What is silanation?
dental glass fibres are always pretreated with coupling agents ‘silanes’
this helps with adhesion, creating bonds
it improves surface wetting of fibres and allows chemical adhesion between fibres and polymer matrix
what will affect the mechanical properties of the FRC?
direction of fibres
what are the types of directions of fibres?
continuous undirectional
continuous bidirectional
continuous random orientated
discontinuous random orintated (short)
describe unidirectional fibres and their uses?
all fibres in one single direction embedded on the resin
uses; posts, fixed pros (improved tensile strength)
describe bidirectional fibres and their uses?
fibres aligned in 2 directions
uses: dental bridge frameworks, splints, removable dentures (flexural and tensile strength, increased fracture resistance)
describe random orientation fibres and their uses?
fibres randomly dispersed
uses: provisional restorations
(anisotropic properties, cost effective)