C9.2 - Fractional distillation of oil Flashcards

1
Q

There is a great variety of what molecules

A

There is a great variety of hydrocarbon molecules

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2
Q

There is a great variety of hydrocarbon molecules.

What are some?

A

Some hydrocarbon molecules are quite small

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3
Q

There is a great variety of hydrocarbon molecules.
Some hydrocarbon molecules are quite small, with relatively few carbon atoms in short chains.
What do these short-chain molecules make up?

A

These short-chain molecules make up the hydrocarbons that tend to be most useful

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4
Q

There is a great variety of hydrocarbon molecules.
Some hydrocarbon molecules are quite small, with relatively few carbon atoms in short chains.
These short-chain molecules make up the hydrocarbons that tend to be most useful.
Why do these short-chain hydrocarbons make good fuels?

A

These short-chain hydrocarbons make good fuels, because they:

  1. Ignite easily
  2. Burn well, with less smoky flames than hydrocarbons made up of larger molecules
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5
Q

Short-chain hydrocarbons make good fuels, as they ignite easily and burn well, with less smoky flames than hydrocarbons made up of larger molecules.
What are they described as?

A

Short-chain hydrocarbons are described as very flammable

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6
Q

Flammable

A

Flammable is:

  1. Easily ignited
  2. Capable of burning rapidly
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7
Q

There is a great variety of hydrocarbon molecules.
Some are quite small, with relatively few carbon atoms in short chains.
These short-chain molecules make up the hydrocarbons that tend to be most useful.
What do other hydrocarbons have?

A

Other hydrocarbons:

  1. Have lots of carbon atoms in their long-chain molecules
  2. May have branches (side-chains) or form rings
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8
Q

What do the properties of hydrocarbons depend on?

A

The properties of hydrocarbons depend on the chain length of their molecules

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9
Q

Boiling point

A

Boiling point is the temperature at which the:
1. Liquid boils
Or,
2. Gas condenses

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10
Q

Volatility

A

Volatility is the tendency to turn into a gas

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11
Q

Viscosity

A

Viscosity is how easily it flows

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12
Q

Flammability

A

Flammability is how easily it burns

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13
Q

As the size of the molecule increases (long chain), what happens to the boiling point?

A

As the size of the molecule increases (long chain), the boiling point increases

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14
Q

As the size of the molecule increases (long chain), what happens to the volatility?

A

As the size of the molecule increases (long chain), the volatility decreases

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15
Q

As the size of the molecule increases (long chain), what happens to the viscosity?

A

As the size of the molecule increases (long chain), the viscosity increases

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16
Q

As the size of the molecule increases (long chain), what happens to the flammability?

A

As the size of the molecule increases (long chain), the flammability decreases

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17
Q

Low viscosity

A

Low viscosity means very runny

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18
Q

High viscosity

A

High viscosity means thick

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19
Q

Lower flammability

A

Lower flammability means a smokier flame

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20
Q

What is crude oil separated into?

A

Crude oil is separated into hydrocarbons with similar boiling points, called fractions

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21
Q

Crude oil is separated into hydrocarbons with similar boiling points, called fractions.
What is this process called?

A

This process is called fractional distillation

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22
Q

Fractional distillation

A

Fractional distillation is a way to separate liquids from a mixture of liquids by:

  1. Boiling off the substances at different temperatures
  2. Then condensing and collecting the liquids
23
Q

Crude oil is separated into hydrocarbons with similar boiling points, called fractions.
This process is called fractional distillation.
What does each hydrocarbon fraction contain?

A

Each hydrocarbon fraction contains molecules with similar numbers of carbon atoms

24
Q

Crude oil is separated into hydrocarbons with similar boiling points, called fractions.
This process is called fractional distillation.
Each hydrocarbon fraction contains molecules with similar numbers of carbon atoms.
What does each of these fractions do?

A

Each of these fractions boils at a different temperature range

25
Crude oil is separated into hydrocarbons with similar boiling points, called fractions. This process is called fractional distillation. Each hydrocarbon fraction contains molecules with similar numbers of carbon atoms. Why does each of these fractions boil at a different temperature range?
Each of these fractions boils at a different temperature range, because of the different sizes of the molecules in it
26
What does the boiling point of a hydrocarbon depend on?
The boiling point of a hydrocarbon depends on the size of its molecules
27
The boiling point of a hydrocarbon depends on the size of its molecules. What can be used to separate the hydrocarbons in crude oil into fractions?
Differences in boiling points can be used in fractional distillation to separate the hydrocarbons in crude oil into fractions
28
What happens to the crude oil before it goes into the tower?
The crude oil is vaporised before it goes into the tower
29
The crude oil is vaporised before it goes into the tower. | What is at the bottom of the tower, at over 350 degrees Celsius, there is what?
At the bottom of the tower, at over 350 degrees Celsius, there is residue
30
At the bottom of the tower, at over 350 degrees Celsius, there is residue. This is a very thick, sticky mixture of long-chain hydrocarbons. What the residue used in?
The residue at the bottom of the tower is used in making: 1. Roads 2. Flat roofs
31
The crude oil is vaporised before it goes into the tower. | What is the 1st fraction?
The 1st fraction is diesel oil/gas oil
32
The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. What is diesel oil/gas oil used as?
Diesel oil/gas oil is used as: 1. Fuel in diesel engines 2. Boiler fuel
33
The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. What is the 2nd fraction?
The 2nd fraction is kerosene
34
The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. The 2nd fraction is kerosene. What is kerosene used for?
Kerosene is used for aircraft fuel
35
The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. The 2nd fraction is kerosene. What is the 3rd fraction?
The 3rd fraction is gasoline/petrol
36
``` The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. The 2nd fraction is kerosene. The 3rd fraction is gasoline/petrol. What is gasoline/petrol used for? ```
Gasoline/petrol is used for fuel in car engines
37
``` The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. The 2nd fraction is kerosene. The 3rd fraction is gasoline/petrol. What is the 4th fraction? ```
The 4th fraction is refinery/petroleum gas (short-chain hydrocarbons and low boiling point alkanes)
38
The crude oil is vaporised before it goes into the tower. The 1st fraction is diesel oil/gas oil. The 2nd fraction is kerosene. The 3rd fraction is gasoline/petrol. The 4th fraction is refinery/petroleum gas (short-chain hydrocarbons and low boiling point alkanes). What is refinery/petroleum gas (short-chain hydrocarbons and low boiling point alkanes) used as?
Refinery/petroleum gas (short-chain hydrocarbons and low boiling point alkanes) is used as fuel
39
The temperature at the 4th fraction of the tower
The temperature at the 4th fraction of the tower is 50 degrees Celsius
40
What is headed and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour?
Crude oil is: 1. Heated 2. Fed in near the bottom of a tall tower (called a fractionating column) as hot vapour
41
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. How is the column kept?
The column is kept: 1. Very hot at the bottom 2. Much cooler at the top
42
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. The column is kept very hot at the bottom and much cooler at the top, so the temperature decreases going up the column. What do the gases do?
The gases move up the column
43
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. The column is kept very hot at the bottom and much cooler at the top, so the temperature decreases going up the column. The gases move up the column and the hydrocarbons condense when they reach the temperature of their boiling points. How are the different fractions collected?
The different fractions are collected as liquids at different levels
44
Hydrocarbons with the smallest molecules have the lowest what?
Hydrocarbons with the smallest molecules have the lowest boiling points
45
Hydrocarbons with the smallest molecules have the lowest boiling points. Where are they piped out?
Hydrocarbons with the smallest molecules are piped out of the cooler top of the column as gases
46
Hydrocarbons with the smallest molecules have the lowest boiling points. They are piped out of the cooler top of the column as gases. At the bottom of the column, the fractions have high what?
At the bottom of the column, the fractions have high boiling points
47
Hydrocarbons with the smallest molecules have the lowest boiling points. They are piped out of the cooler top of the column as gases. At the bottom of the column, the fractions have high boiling points. What do they do?
``` The fractions at the bottom of the column with high boiling points cool to form very thick: 1. Liquids Or, 2. Solids at room temperature ```
48
Once collected from the fractionating column, what do the fractions need before they can be used?
Once collected from the fractionating column, the fractions need more processing before they can be used
49
There is a great variety of hydrocarbon molecules. | Some hydrocarbon molecules are quite small, with what?
Some hydrocarbon molecules are quite small, with relatively few carbon atoms in short chains
50
The crude oil is vaporised before it goes into the tower. At the bottom of the tower, at over 350 degrees Celsius, there is residue. This is what?
This is a very thick, sticky mixture of long-chain hydrocarbons
51
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. The column is kept very hot at the bottom and much cooler at the top, so what?
The column is kept: 1. Very hot at the bottom 2. Much cooler at the top ,so the temperature decreases going up the column
52
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. The column is kept very hot at the bottom and much cooler at the top, so the temperature decreases going up the column. The gases move up the column and the hydrocarbons do what?
The: 1. Gases move up the column 2. Hydrocarbons condense when they reach the temperature of their boiling points
53
Crude oil is heated and fed in near the bottom of a tall tower (called a fractionating column) as hot vapour. The column is kept very hot at the bottom and much cooler at the top, so the temperature decreases going up the column. The gases move up the column and the hydrocarbons condense when they reach the temperature of their boiling points. The different fractions are collected as liquids at different levels. How are the fractions collected from the column?
The fractions are collected from the column in a continuous process