C8.9 - Altering conditions Flashcards
In general, the position of equilibrium does what?
In general, the position of equilibrium shifts as if trying to cancel out any change in conditions
When you increase the concentration of a reactant, this will cause the position of equilibrium to do what?
When you increase the concentration of a reactant, this will cause the position of equilibrium to shift to the right, in favour of the products
In many reversible reactions, there are what?
In many reversible reactions, there are more molecules of gas on 1 side of the equation than on the other
In many reversible reactions, there are more molecules of gas on 1 side of the equation than on the other.
By changing the pressure at which the reaction is carried out, what can you change?
By changing the pressure at which the reaction is carried out, you can change the amount of products that are made
If the forward reaction produces more molecules of gas, an increase in pressure does what?
If the forward reaction produces more molecules of gas, an increase in pressure decreases the amounts of products formed
If the forward reaction produces fewer molecules of gas, an increase in pressure does what?
If the forward reaction produces fewer molecules of gas, an increase in pressure increases the amount of products formed
Brown gas is 2NO2 (g).
Pale yellow gas is N2O4 (g).
If you increase the pressure in the reaction vessel, the position of equilibrium will shift to reduce the pressure
It will move in favour of the reaction that produces fewer gas molecules.
In this case, what would happen?
In this case, that is to the right, in favour of the forward reaction, so:
- More N2O4 gas will be made
- The colour of the gaseous mixture will get lighter
Changing the pressure affects the equilibrium only if there are what?
Changing the pressure affects the equilibrium only if there are different numbers of molecules of gases on each side of the balanced equation
What happens when you have a closed system?
When you have a closed system, no substances are: 1. Added Or, 2. Taken away from the reaction mixture
When you have a closed system, no substances are added or taken away from the reaction mixture.
In a closed system, what do the relative amounts of the reactants and products in a reversible reaction at equilibrium depend on?
In a closed system, the relative amounts of the:
1. Reactants
2. Products
in a reversible reaction at equilibrium depend on the temperature
By changing the temperature, what can you plan to do?
By changing the temperature, you can plan to get:
- More of the products
- Less of the reactants
If the forward reaction is exothermic, an increase in temperature does what?
If the forward reaction is exothermic, an increase in temperature decreases the amount of products formed
If the forward reaction is endothermic, an increase in temperature does what?
If the forward reaction is endothermic, an increase in temperature increases the amount of products formed
When you increase the concentration of a reactant, this will cause the position of equilibrium to shift to the right, in favour of the products, in order to do what?
When you increase the concentration of a reactant, this will cause the position of equilibrium to shift to the right, in favour of the products, in order to reduce the concentration of that reactant
When you increase the concentration of a reactant, this will cause the position of equilibrium to shift to the right, in favour of the products, in order to reduce the concentration of that reactant.
It opposes what?
It opposes the change that is introduced
If the forward reaction produces more molecules of gas, a decrease in pressure does what?
If the forward reaction produces more molecules of gas, a decrease in pressure increases the amounts of products formed
If the forward reaction produces fewer molecules of gas, a decrease in pressure does what?
If the forward reaction produces fewer molecules of gas, a decrease in pressure decreases the amount of products formed
Changing the pressure affects the equilibrium only if there are different numbers of molecules of gases on each side of the balanced equation
However, increasing the pressure will do what?
Increasing the pressure will speed up both the:
1. Forward
2. Reverse
reactions by the same amount
If the forward reaction is exothermic, a decrease in temperature does what?
If the forward reaction is exothermic, a decrease in temperature increases the amount of products formed
If the forward reaction is endothermic, a decrease in temperature does what?
If the forward reaction is endothermic, a decrease in temperature decreases the amount of products formed