Buffers and Titration (5/11) Flashcards
Buffer
A solution that resists change in pH when an acid or base is added. It is created from a mixture of a weak acid and its conjugate base or vise versa
Henderson-Hasselbalch
pH = pKa + log[A-]/[HA]
Bicarbonate buffering system
weak acid of bicarbonate and weak base of HCO3-
When adding an acid or the solution…
[A-] become [A- - 1] and [HA] becomes [HA + 1]
If more acid than conjugate base in initial solution…
then, buffering capacity decreases
Neutralization point
Moles of equivalents of acid = mole of equivalents of base
Normality Equation
N=[moles OH]/liters of solution
For mono or diprotic reaction
nC1V1=nC2V2
where n=1 for mono
n is the number of H+ ions or OH- ions
Indicators
weak acids or bases that take on colors when protonated or deprotonated (changes in pH)
Equivalence point
moles acid=moles base and is fully neutralized
Half equivalence point
half titrate needed to add to reach equivalence point is added
Weak acid/strong base
neutralization is always above a pH of 7