Bio Chapter 1 Flashcards
Atom
The smallest unit of an element that retains all the properties of the element.
Proton, Neutron, Electron
Molecule
Two or more atoms chemically linked.
Matter
Anything that occupies space and has a mass.
Trace elements
Mo, Zn, Cu
Main Bio elements
C, H, O, N P, S
Mass of atoms
Neutron>Proton>Electron
Nucleons
Protons and Neutrons
Neutron # =
Mass # - Atomic #
H2O Universal Solvent
High boiling, melting, delta H vaporization, dipole
Bent molecule, 105 degrees, and polar molecule capable of forming 4 H bonds
H bond
F,O,N
Intra and intermolecular
Nonpolar covalent bond
Molecules share electrons equally.
Polar bond
Unequal sharing of electrons.
Ionic bonds
Electrons transferred between a metal and non metal.
N+ is a sign of an ionic bond.
Ionic compounds
NaCl, MgBr2, NH4Cl
Most polar molecules and ionic compounds are water soluble.
Why can’t hydrocarbons dissolve in water?
Water molecules have extensive H bonds that would have to break to make room for hydrophobic solute. Not spontaneous.
Surface of proteins charges
Charges are hydrophilic. H20 is very polar and shields the charges from each other. Interior of the protein charges interact strongly.
H20 electrostatic interactions
H20 diminishes the charge by forming solvent shell which produces an electric field which opposes ion fields.
ΔG Free Energy
ΔG = ΔH - TΔS
Endergonic: +ΔH, +ΔG
Exergonic: -ΔH, -ΔG
Guanranteed Spontaneous ΔG
-ΔH and +ΔS will be spontaneous at all temperatures.
K= Products/ Reactants
No solids or pure liquids
K»1 favors products, K«1 favors reactants
ΔG= -2.303RTLogK or ΔG=-RTlnK
pH equations
pH= -log[H3O+]
pOH= -log[OH-]
pH= pH + pOH
Large Ka = small pKa
Henderson Hasselback Equation
Buffers
pH = pKa + Log [Base/Acid]
Energy Main categories
Kinetic and Potential
Other types: Gravitation, Electrical, Thermal, Nuclear, Mechanical, Magnetic
Temperature
Average kinetic energy measured
F= 1.8C + 23
K= C+273
1st Law Thermodynamics
Normal conditions, energy can not be created nor destroyed. Only transferred or changed.
2nd Law Thermodynamics
Entropy of the universe is always increasing. No heat transfer is 100% efficient.
3rd Law Thermodynamics
As temperature approaches absolute zero, entropy is at a minimum.
Systems of Heat
Open system: mass and energy can exchange
E.g. H20 in open container
Closed: allows energy to transfer, no mass
E.g. H20 in a flask
Isolated: neither energy nor mass can transfer
E.g. H20 in a flask in a vacuum.
S->L
Melting (+ΔH)
Heat of fusion
L->S
Freezing (-ΔH)
L->G
Vaporization (boiling) (+ΔH)
G->L
Condensing (-ΔH)