3.3.1.3 Isomerism Flashcards

1
Q

What is an isomer?

A

A molecule with the same molecular formula but a different arrangement of atoms

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2
Q

What is structural isomerism?

A

Where molecules have the same molecular formula but with a different connectivity

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3
Q

What is chain isomerism?

A

When the hydrocarbon chain is arranged differently, such as branching

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4
Q

What is positional isomerism?

A

When the functional group is attached to the main chain at different points

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5
Q

What is functional group isomerism?

A

When there are different functional groups

E.g. C - C - O becomes C - O - C

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6
Q

What is stereoisomerism?

A

When the structural formula is the same but differ in the arrangement of the bonds in space

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7
Q

What is the Cahn Ingold Prelog system?

A

In a carbon chain, the direct atom attached to the carbon involved in the double bon is ranked based on the atomic a number
A higher atomic number = a higher priority

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8
Q

Why does the Cahn Ingold Prelog system not always work?

A

It fails when there are more than 2 groups

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9
Q

What is EZ isomerism?

A

The different positions of groups on either side of the double bond
Z = same side
E = different side

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10
Q

What is the difference between structural and stereo isomerism?

A

Different connectivity vs different orientation of atoms

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