3.1.11.1 Electrode Potentials and Cells Flashcards

1
Q

What are the standard conditions?

A

298K
100kPa
1M solution

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2
Q

What does a cell diagram look like?

A

Metal (s) | Ion (aq) || Ion (aq) | Metal (s)

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3
Q

What do the vertical lines translate to in a cell diagram?

A

= phase boundary, || = salt bridge

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4
Q

What is the standard half cell?

A

Hydrogen

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5
Q

What occurs when two half cells are connected?

A

A cell is created where only overall reversible reaction is formed

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6
Q

What is the salt bridge made of?

A

A strip of filter paper soaked in saturated potassium nitrate solution

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7
Q

Does the e value change with a change in moles?

A

No

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8
Q

Which side does each species go on in a cell diagram?

A

More negative cell goes on the left
Species on the left is an oxidising agent
Species on the right is a reducing agent

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9
Q

How do you write the overall reaction for an electrochemical cell?

A

Write out the two half cell equations with the more negative equation above the other
Multiply until the number of electrons lost/gained in each is equal
Bottom left reacts with top right

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10
Q

What is the purpose of the salt bridge in an electrochemical cell?

A

Allows the movement of ions associated with the metals

This balances the charges by the movement of positive or negative ions in solution

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11
Q

What is the purpose of the wire in an electrochemical cell?

A

It completes the circuit by allowing the movement of electrons

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12
Q

Can group 1 or 2 be used in an electrochemical cell?

A

No as they would react with the water

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13
Q

What does an electrochemical cell look like?

A

See card

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