3.1.11.1 Electrode Potentials and Cells Flashcards
What are the standard conditions?
298K
100kPa
1M solution
What does a cell diagram look like?
Metal (s) | Ion (aq) || Ion (aq) | Metal (s)
What do the vertical lines translate to in a cell diagram?
= phase boundary, || = salt bridge
What is the standard half cell?
Hydrogen
What occurs when two half cells are connected?
A cell is created where only overall reversible reaction is formed
What is the salt bridge made of?
A strip of filter paper soaked in saturated potassium nitrate solution
Does the e value change with a change in moles?
No
Which side does each species go on in a cell diagram?
More negative cell goes on the left
Species on the left is an oxidising agent
Species on the right is a reducing agent
How do you write the overall reaction for an electrochemical cell?
Write out the two half cell equations with the more negative equation above the other
Multiply until the number of electrons lost/gained in each is equal
Bottom left reacts with top right
What is the purpose of the salt bridge in an electrochemical cell?
Allows the movement of ions associated with the metals
This balances the charges by the movement of positive or negative ions in solution
What is the purpose of the wire in an electrochemical cell?
It completes the circuit by allowing the movement of electrons
Can group 1 or 2 be used in an electrochemical cell?
No as they would react with the water
What does an electrochemical cell look like?
See card