3.1.3.2 Nature of Covalent and Dative Covalent Bonds Flashcards

1
Q

What is dative covalent bonding?

A

When both of the shared electrons come from the same atom

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2
Q

What are the properties of small covalent bonds?

A

Low melting/boiling points
Don’t conduct electricity
Are electrical insulators
Small covalent molecules that are polar or can form hydrogen bonds are soluble

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3
Q

What are the properties of giant covalent bonds?

A

Extremely high melting/boiling points
Electrical insulators
Don’t conduct electricity
Aren’t soluble in water

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4
Q

What are covalent bonds?

A

Where atoms share electrons to have a noble gas arrangement

Formed between a pair of non-metal atoms

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5
Q

What is a molecule?

A

A small group of covalently bonded atoms

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6
Q

How does a covalent bond work?

A

The atoms are held together by the electrostatic attraction between the nuclei and shared electrons

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7
Q

How do you represent two shared electrons in a covalent bond?

A

By a double line

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8
Q

Why do covalent bonds have low melting/boiling points?

A

The inter-molecular forces are weak even though covalent bonds are strong

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9
Q

Do covalent bonds conduct electricity?

A

No, they’re neutral molecules and there are no charged particles to carry the current so they’re poor conductors

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10
Q

Which atom accepts two electrons in a dative covalent bond?

A

The atom that doesn’t have a full outer shell (electron-deficient)

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11
Q

Which atom donates two electrons in a dative covalent bond?

A

The atom that is donating electrons has a pair of electrons that isn’t being used
Called a lone pair

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12
Q

How do you express a dative covalent bond?

A

With an arrow that points towards the atom accepting the pair

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13
Q

Why is it hard to break a covalent bond?

A

You have to put in energy to overcome the attraction in order to form a covalent bond

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14
Q

How do you work out the charge of a covalent bond?

A

Protons minus electrons

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15
Q

What are the types of bond in a double bond?

A

Sigma bond: between the nuclei of the two atoms

Pi bond: second pair of electrons

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16
Q

What does the strength of covalent bonds depend on?

A

Bond length: distance between nuclei, dependent on the atomic radii, longer bonds have a weaker bond
Pi bonds are weaker than sigma bonds, double bond is weaker than a single bond
Pi bonds are likely to be attacked by electrophiles because the delocalisation of the electrons makes them easier to access

17
Q

Do covalent bond conduct heat?

A

No as the molecules are not close enough to carry heat through the structure