15A.3 Flashcards
what does bimolecular mechanism
a mechanism in which two species are reacting in the rate determining step
in transition state the sign goes
on the outside
in Sn2 what happens after the transition state
the arrangements of the groups that remain attached to the central atom has been inverted
in Sn2 the optical activity of the product are reactant would be
opposite to each other (because of the inversion) so if the reactant is laevoratatory then the product is dextrorotatory
how can we find out if the mechanism that occurred is Sn2
by seeing if the optical activity of the product and the reactant are opposite to each other
what is unimolecular mechanism
a mechanism in which only one species is reacting in the rate-determining step
why is a racemic solution formed during Sn1
because it occurs in two steps where the first step forms is carbocation with a planar shape, which means when the negative OH comes to attack it has a 50% chance to attack on each side so two enantiomers with the same ratio form making a racemic solution
how can we find out if the reaction has occurred through Sn1
by measuring the optical activity of the product and reactant where if the reactant has optical activity and the product doesn’t that means its Sn1